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铜催化甲醇与二胺脱氢偶联合成氢气

Copper-Catalyzed Hydrogen Production through the Dehydrogenative Coupling of Methanol and Diamine.

作者信息

Cheng Danyang, Yu Shixiang, Wang Meng, Ma Ding

机构信息

Beijing National Laboratory for Molecular Sciences, New Cornerstone Science Laboratory, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.

出版信息

Precis Chem. 2024 Mar 6;2(4):138-142. doi: 10.1021/prechem.3c00113. eCollection 2024 Apr 22.

DOI:10.1021/prechem.3c00113
PMID:39473529
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11504178/
Abstract

A hydrogen storage system was developed via heterogeneous catalysis, employing the dehydrogenative coupling of methanol and ,'-dimethylethylenediamine to efficiently produce high-purity H. In this process, the Cu/ZnO/AlO catalyst displayed superior activity in hydrogen production, with Cu identified as the major active site through comprehensive characterization.

摘要

通过多相催化开发了一种储氢系统,该系统利用甲醇与N,N'-二甲基乙二胺的脱氢偶联反应高效生产高纯度氢气。在此过程中,Cu/ZnO/Al₂O₃催化剂在制氢方面表现出优异的活性,通过综合表征确定Cu为主要活性位点。

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本文引用的文献

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Shape-Controlled Pathways in the Hydrogen Production from Ethanol Steam Reforming over Ceria Nanoparticles.氧化铈纳米颗粒上乙醇蒸汽重整制氢过程中的形状控制路径
ACS Catal. 2022 Aug 19;12(16):10482-10498. doi: 10.1021/acscatal.2c02117. Epub 2022 Aug 10.
2
Inverse ZrO/Cu as a highly efficient methanol synthesis catalyst from CO hydrogenation.反相ZrO/Cu作为一种用于CO加氢制甲醇的高效催化剂。
Nat Commun. 2020 Nov 13;11(1):5767. doi: 10.1038/s41467-020-19634-8.
3
A Reversible Liquid Organic Hydrogen Carrier System Based on Methanol-Ethylenediamine and Ethylene Urea.
基于甲醇 - 乙二胺和乙烯脲的可逆液体有机氢载体系统
Angew Chem Int Ed Engl. 2019 Apr 1;58(15):5105-5109. doi: 10.1002/anie.201901695. Epub 2019 Mar 6.
4
2-(N-Methylbenzyl)pyridine: A Potential Liquid Organic Hydrogen Carrier with Fast H Release and Stable Activity in Consecutive Cycles.2-(N-甲基苄基)吡啶:一种具有快速 H 释放和在连续循环中稳定活性的潜在液体有机氢载体。
ChemSusChem. 2018 Feb 22;11(4):661-665. doi: 10.1002/cssc.201702256. Epub 2018 Jan 18.
5
Reversible Interconversion between 2,5-Dimethylpyrazine and 2,5-Dimethylpiperazine by Iridium-Catalyzed Hydrogenation/Dehydrogenation for Efficient Hydrogen Storage.铱催化加氢/脱氢实现 2,5-二甲基吡嗪和 2,5-二甲基哌嗪的可逆互变用于高效储氢。
Angew Chem Int Ed Engl. 2017 Aug 28;56(36):10886-10889. doi: 10.1002/anie.201705452. Epub 2017 Jul 27.
6
Efficient Reversible Hydrogen Carrier System Based on Amine Reforming of Methanol.基于甲醇胺重整的高效可逆储氢系统。
J Am Chem Soc. 2017 Feb 22;139(7):2549-2552. doi: 10.1021/jacs.6b11637. Epub 2017 Feb 9.
7
Low-Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogeneous Cobalt Catalyst.低温二氧化碳加氢制甲醇用均相钴催化剂。
Angew Chem Int Ed Engl. 2017 Feb 6;56(7):1890-1893. doi: 10.1002/anie.201609077. Epub 2017 Jan 12.
8
Catalytic Reforming of Oxygenates: State of the Art and Future Prospects.含氧物的催化重整:现状与未来展望。
Chem Rev. 2016 Oct 12;116(19):11529-11653. doi: 10.1021/acs.chemrev.6b00099. Epub 2016 Aug 16.
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Rechargeable Hydrogen Storage System Based on the Dehydrogenative Coupling of Ethylenediamine with Ethanol.基于乙二胺与乙醇脱氢偶联的可充电储氢系统。
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