铜催化甲醇与二胺脱氢偶联合成氢气
Copper-Catalyzed Hydrogen Production through the Dehydrogenative Coupling of Methanol and Diamine.
作者信息
Cheng Danyang, Yu Shixiang, Wang Meng, Ma Ding
机构信息
Beijing National Laboratory for Molecular Sciences, New Cornerstone Science Laboratory, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
出版信息
Precis Chem. 2024 Mar 6;2(4):138-142. doi: 10.1021/prechem.3c00113. eCollection 2024 Apr 22.
A hydrogen storage system was developed via heterogeneous catalysis, employing the dehydrogenative coupling of methanol and ,'-dimethylethylenediamine to efficiently produce high-purity H. In this process, the Cu/ZnO/AlO catalyst displayed superior activity in hydrogen production, with Cu identified as the major active site through comprehensive characterization.
通过多相催化开发了一种储氢系统，该系统利用甲醇与N,N'-二甲基乙二胺的脱氢偶联反应高效生产高纯度氢气。在此过程中，Cu/ZnO/Al₂O₃催化剂在制氢方面表现出优异的活性，通过综合表征确定Cu为主要活性位点。
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