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含铝/聚四氟乙烯反应材料的铝热炸药的能量输出性能。

Energy output performance of aluminized explosive containing Al/PTFE reactive materials.

作者信息

Jiang Fan, Sun Peipei, Bu Yufan, Niu Yulei, Li Yuanyuan, Zhang Kun, Wang Xiaofeng, Nan Hai

机构信息

Xi'an Modern Chemistry Research Institute China.

出版信息

RSC Adv. 2024 Oct 29;14(46):34348-34355. doi: 10.1039/d4ra01476f. eCollection 2024 Oct 23.

Abstract

In this paper, a series of CL-20 based explosive formulations containing Al/PTFE reactive materials are designed using a self-designed closed explosion test device. The quasi-static pressure (QSP) and peak temperature of the explosive reaction are studied under different mass percentages of Al/PTFE and different charge structures. The composition and morphology of the solid residue products after the explosion were analyzed, proving the feasibility of using Al/PTFE in explosives and providing theoretical support for the design of the aluminized explosive in this system. The results show that a high content of Al/PTFE reactive material can be successfully detonated by CL-20. Using CL-20 as the central explosive column can make pure Al/PTFE react, but this will result in a decrease in QSP by about 25%. The mass ratio of 75/25 has the highest QSP, which can reach 0.289, 0.310, 0.270 and 0.218 MPa. The three samples in G2 exhibit the highest equilibrium temperature, with G2A, G2B and G2C reaching 868.2 °C, 942.0 °C and 626.2 °C, respectively. Regardless of the charge structure, the equilibrium temperatures after explosion of Al/PTFE at ratios of 75/25 and 70/30 are higher than those of 60/40. When the proportion of Al/PTFE is 60/40, the equilibrium temperature after explosion will decrease by nearly 20%. XRD revealed that the solid residue mainly comprises Al, α-AlO and γ-AlO. No C element was found in the solid product, indicating that the C element mainly exists in a gaseous state after the explosion.

摘要

本文利用自行设计的密闭爆炸试验装置,设计了一系列含铝粉/聚四氟乙烯(Al/PTFE)反应性材料的六硝基六氮杂异伍兹烷(CL-20)基混合炸药配方。研究了不同Al/PTFE质量比和不同装药结构下炸药反应的准静态压力(QSP)和峰值温度。分析了爆炸后固体残渣产物的组成和形貌,验证了Al/PTFE在炸药中应用的可行性,为该体系含铝炸药的设计提供了理论支持。结果表明,高含量的Al/PTFE反应性材料能够被CL-20成功引爆。以CL-20作为中心药柱可使纯Al/PTFE发生反应,但这会导致QSP下降约25%。质量比为75/25时QSP最高,可达0.289、0.310、0.270和0.218兆帕。G2组中的三个样品表现出最高的平衡温度,G2A、G2B和G2C分别达到868.2℃、942.0℃和626.2℃。无论装药结构如何,Al/PTFE质量比为75/25和70/30时爆炸后的平衡温度均高于60/40时的平衡温度。当Al/PTFE比例为60/40时,爆炸后的平衡温度将降低近20%。X射线衍射(XRD)分析表明,固体残渣主要由Al、α-AlO和γ-AlO组成。在固体产物中未发现C元素,表明C元素在爆炸后主要以气态存在。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77bb/11519855/87d297f21faf/d4ra01476f-f1.jpg

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