Jiang Fan, Sun Peipei, Bu Yufan, Niu Yulei, Li Yuanyuan, Zhang Kun, Wang Xiaofeng, Nan Hai
Xi'an Modern Chemistry Research Institute China.
RSC Adv. 2024 Oct 29;14(46):34348-34355. doi: 10.1039/d4ra01476f. eCollection 2024 Oct 23.
In this paper, a series of CL-20 based explosive formulations containing Al/PTFE reactive materials are designed using a self-designed closed explosion test device. The quasi-static pressure (QSP) and peak temperature of the explosive reaction are studied under different mass percentages of Al/PTFE and different charge structures. The composition and morphology of the solid residue products after the explosion were analyzed, proving the feasibility of using Al/PTFE in explosives and providing theoretical support for the design of the aluminized explosive in this system. The results show that a high content of Al/PTFE reactive material can be successfully detonated by CL-20. Using CL-20 as the central explosive column can make pure Al/PTFE react, but this will result in a decrease in QSP by about 25%. The mass ratio of 75/25 has the highest QSP, which can reach 0.289, 0.310, 0.270 and 0.218 MPa. The three samples in G2 exhibit the highest equilibrium temperature, with G2A, G2B and G2C reaching 868.2 °C, 942.0 °C and 626.2 °C, respectively. Regardless of the charge structure, the equilibrium temperatures after explosion of Al/PTFE at ratios of 75/25 and 70/30 are higher than those of 60/40. When the proportion of Al/PTFE is 60/40, the equilibrium temperature after explosion will decrease by nearly 20%. XRD revealed that the solid residue mainly comprises Al, α-AlO and γ-AlO. No C element was found in the solid product, indicating that the C element mainly exists in a gaseous state after the explosion.
本文利用自行设计的密闭爆炸试验装置,设计了一系列含铝粉/聚四氟乙烯(Al/PTFE)反应性材料的六硝基六氮杂异伍兹烷(CL-20)基混合炸药配方。研究了不同Al/PTFE质量比和不同装药结构下炸药反应的准静态压力(QSP)和峰值温度。分析了爆炸后固体残渣产物的组成和形貌,验证了Al/PTFE在炸药中应用的可行性,为该体系含铝炸药的设计提供了理论支持。结果表明,高含量的Al/PTFE反应性材料能够被CL-20成功引爆。以CL-20作为中心药柱可使纯Al/PTFE发生反应,但这会导致QSP下降约25%。质量比为75/25时QSP最高,可达0.289、0.310、0.270和0.218兆帕。G2组中的三个样品表现出最高的平衡温度,G2A、G2B和G2C分别达到868.2℃、942.0℃和626.2℃。无论装药结构如何,Al/PTFE质量比为75/25和70/30时爆炸后的平衡温度均高于60/40时的平衡温度。当Al/PTFE比例为60/40时,爆炸后的平衡温度将降低近20%。X射线衍射(XRD)分析表明,固体残渣主要由Al、α-AlO和γ-AlO组成。在固体产物中未发现C元素,表明C元素在爆炸后主要以气态存在。