Tanguy Nicolas R, Rajabi-Abhari Araz, Williams-Linera Eric, Miao Zheyuan, Tratnik Nicole, Zhang Xiao, Hao Cheng, Virya Alvin, Yan Ning, Lagadec Ronan Le
Instituto de Química, Universidad Nacional Autónoma de México, Ciudad de México, 04510, México.
Centro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México, Querétaro, Querétaro, 76230, México.
Macromol Rapid Commun. 2024 Dec;45(23):e2400418. doi: 10.1002/marc.202400418. Epub 2024 Oct 30.
Wearable strain transducers are poised to transform the field of healthcare owing to the promise of personalized devices capable of real-time collection of human physiological health indicators. For instance, monitoring patients' progress following injury and/or surgery during physiotherapy is crucial but rarely performed outside clinics. Herein, multifunctional liquid-free ionic elastomers are designed through the volume effect and the formation of dynamic hydrogen bond networks between polyvinyl alcohol (PVA) and weak acids (phosphoric acid, phytic acid, formic acid, citric acid). An ultra-stretchable (4600% strain), highly conducting (10 mS cm), self-repairable (77% of initial strain), and adhesive ionic elastomer is obtained at high loadings of phytic acid (4:1 weight to PVA). Moreover, the elastomer displayed durable performances, with intact mechanical properties after a year of storage. The elastomer is used as a transducer to monitor human motions in a device comprising an ESP32-based development board. The device detected walking and/or running biomechanics and communicated motion-sensing data (i.e., amplitude, frequency) wirelessly. The reported technology can also be applied to other body parts to monitor recovery after injury and/or surgery and inform practitioners of motion biomechanics remotely and in real time to increase convalescence effectiveness, reduce clinic appointments, and prevent injuries.
可穿戴应变传感器有望改变医疗保健领域,因为这类个性化设备能够实时收集人体生理健康指标。例如,在物理治疗期间监测患者受伤和/或手术后的恢复情况至关重要,但在诊所之外很少进行。在此,通过体积效应以及聚乙烯醇(PVA)与弱酸(磷酸、植酸、甲酸、柠檬酸)之间动态氢键网络的形成,设计出了多功能无液离子弹性体。在高负载量的植酸(与PVA的重量比为4:1)下,可获得一种超拉伸(4600%应变)、高导电(10 mS cm)、可自我修复(初始应变的77%)且具有粘性的离子弹性体。此外,该弹性体表现出持久的性能,储存一年后机械性能仍保持完好。该弹性体被用作传感器,在一个包含基于ESP32的开发板的设备中监测人体运动。该设备检测到行走和/或跑步的生物力学信息,并无线传输运动传感数据(即振幅、频率)。所报道的技术还可应用于身体的其他部位,以监测受伤和/或手术后的恢复情况,并远程实时地将运动生物力学信息告知从业者,从而提高康复效果、减少门诊预约并预防受伤。