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煤气化细渣流态化熔融燃烧的中试研究。

A pilot scale test on the fluidized melting combustion of coal gasification fine slag.

机构信息

State Key Laboratory of Coal Conversion, Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing 100190, China.

State Key Laboratory of Coal Conversion, Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing 100190, China; Shanxi Key Laboratory of Coal Flexible Combustion and Thermal Conversion, Datong Institute of Coal Clean and Efficient Utilization, Datong 037000, China.

出版信息

Waste Manag. 2024 Dec 15;190:593-599. doi: 10.1016/j.wasman.2024.10.026. Epub 2024 Oct 30.

DOI:10.1016/j.wasman.2024.10.026
PMID:39476646
Abstract

To address the issue of coal gasification fine slag (CGFS) disposal, a novel fluidized melting combustion (FMC) process has been proposed. In this study, the operating feasibility, combustion performance and gas pollutant emission were assessed through 0.4 MW pilot-scale test. The results indicated that both temperature and pressure fluctuation remained within the controllable range throughout entire test period. Under the influence of high cycle rate and incomplete combustion, CGFS efficiently achieved the rapid dehydration, preheating and crushing. Some combustible H and CO were generated simultaneously. After the preheating modification, the refractory CGFS transformed into hot gas-solid composite fuel. To achieve the complete carbon removal and ash vitrification, the melting combustion temperature was up to 1501.1 °C. Under the excessively high temperature, liquid slag was discharged smoothly from the tap hole without any observed blockage. Carbon content in slag was only 0.4 wt%. The slag captured rate and decarbonization rate were up to 79.0 % and 93.8 %, respectively. The initial CO emission was as low as 103.0 mg/m. The initial NO emission reached up to 452.5 mg/m under radiation boiler afterburning. Due to the combined influence of multiple factors, the initial SO emission soared up to 1789.3 mg/m. Further research will focus on controlling flue gas pollutant emissions, resource utilization of molten slag, and developing oxy-combustion. The objective is to attain full carbon neutrality in the entire coal chemical industry process.

摘要

为了解决煤气化细渣(CGFS)处置问题,提出了一种新颖的流化床熔融燃烧(FMC)工艺。本研究通过 0.4MW 中试评估了其运行可行性、燃烧性能和气体污染物排放。结果表明,整个试验期间温度和压力波动均在可控范围内。在高循环率和不完全燃烧的影响下,CGFS 高效地实现了快速脱水、预热和粉碎。同时产生了一些可燃的 H 和 CO。预热改性后,耐火 CGFS 转化为热固复合燃料。为了实现完全脱碳和灰渣玻璃化,熔融燃烧温度高达 1501.1°C。在过高的温度下,液态炉渣从出铁口顺利排出,没有观察到堵塞。渣中的碳含量仅为 0.4wt%。捕渣率和脱碳率分别达到 79.0%和 93.8%。初始 CO 排放量低至 103.0mg/m。在辐射锅炉后燃烧下,初始 NO 排放量达到 452.5mg/m。由于多种因素的综合影响,初始 SO 排放量飙升至 1789.3mg/m。进一步的研究将集中于控制烟气污染物排放、熔融渣的资源利用和开发富氧燃烧。目标是在整个煤化工过程中实现完全的碳中和。

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