Fabricating Porous Alkali-Resistant Resin for Segregation of Perrhenate/Pertechnetate Anions from Wastewater.

The elimination of the β-emitting pertechnetate ion (TcO) from highly alkaline tank waste poses a daunting challenge that is of great significance for nuclear safety and environmental protection. Herein, we report a strategy to fabricate an alkaline-stable porous resin (PANPEI-MeCl) that features hyperbranched quaternary amine groups grafted on the surface and confined within the pores of a superhydrophobic polymer matrix synthesized by a one-pot method, exhibiting a clear superiority both in adsorption kinetics and efficiency compared with available commercial anion-exchange resins applying to TcO capture. Notably, the alkaline stability of the resin can be improved by manipulating the length of side chain alkyl groups, and it shows ultrahigh structural integrity and prominent performance toward acid/alkaline soaking, high-temperature calcination procedures, and high doses of ionizing radiation. Encouraged by its excellent peculiarity, PANPEI-MeCl can continuously capture most of the ReO from the simulated radioactive waste by using a sequential injection automatic separation system.