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合成银和钴纳米粒子,并评估它们对玉米(Zea mays L.)发芽和生物计量参数的影响。

Synthesis of silver and cobalt nanoparticles and assessment of their effects on germination and biometric parameters in maize (Zea mays L.).

机构信息

State University of Maringá, Paraná, Brazil.

State University of Maringá, Paraná, Brazil.

出版信息

Ecotoxicol Environ Saf. 2024 Nov 15;287:117257. doi: 10.1016/j.ecoenv.2024.117257. Epub 2024 Oct 31.

Abstract

Nanomaterials composed of non-nutritive elements are gaining momentum in agriculture. In view of these advances, this study aimed to synthesize and assess the effects of silver (Ag) and cobalt (Co) nanoparticles as seed treatment in maize crops. Nanoparticles were synthesized by coprecipitation and characterized by X-ray diffractometry, transmission electron microscopy, surface area analysis, and Fourier-transform infrared spectroscopy. An experiment was carried out according to a completely randomized design with a 3 × 5 factorial arrangement. The factors were Ag and Co source (soluble, microparticle, and nanoparticle) and concentration (0, 20, 40, 80, and 160 mg L). A total of 50 maize seeds were used per treatment. Seeds were placed on germination paper moistened with distilled water. Germination, biometric parameters (root and shoot lengths), and biomass production were evaluated. Characterization analyses showed that particles ranged from 20 to 100 nm in size and were composed of oxides, such as AgO and CoO. Nanoparticle treatment improved germination and reduced the incidence of defects. The best results were achieved with 98-106 mg L AgO and 75-80 mg L CoO. There was no significant change in biometric parameters between treatments.

摘要

由非营养元素组成的纳米材料在农业中得到了广泛的应用。鉴于这些进展,本研究旨在合成并评估银(Ag)和钴(Co)纳米粒子作为玉米种子处理的效果。纳米粒子通过共沉淀法合成,并通过 X 射线衍射、透射电子显微镜、表面积分析和傅里叶变换红外光谱进行了表征。试验采用完全随机设计,3×5 因子排列。因子是 Ag 和 Co 的来源(可溶性、微粒子和纳米粒子)和浓度(0、20、40、80 和 160mg/L)。每个处理使用 50 颗玉米种子。种子放在湿润的发芽纸上。评价发芽、生物计量参数(根和芽长)和生物量生产。表征分析表明,颗粒尺寸在 20 至 100nm 之间,由 AgO 和 CoO 等氧化物组成。纳米粒子处理提高了发芽率,降低了缺陷发生率。AgO 的最佳浓度为 98-106mg/L,CoO 的最佳浓度为 75-80mg/L。处理之间的生物计量参数没有显著变化。

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