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源自生物质废弃物的生物气凝胶:一种用于废水处理的可持续替代方法。

Bioaerogels from biomass waste: An alternative sustainable approach for wastewater treatment.

作者信息

Priya A K, Alghamdi Huda M, Kavinkumar V, Elwakeel Khalid Z, Elgarahy Ahmed M

机构信息

Department of Chemical Engineering, KPR Institute of Engineering and Technology, Tamilnadu, India.

University of Jeddah, College of Science, Department of Chemistry, Jeddah, Saudi Arabia.

出版信息

Int J Biol Macromol. 2024 Dec;282(Pt 4):136994. doi: 10.1016/j.ijbiomac.2024.136994. Epub 2024 Nov 2.

Abstract

The generation of municipal solid waste is projected to increase from 2.1 billion tonnes in 2023 to 3.8 billion tonnes by 2050. In 2020, the direct global cost of managing this waste was approximately USD 252 billion. When considering additional hidden costs-such as those arising from pollution, adverse health effects, and climate change due to inadequate waste disposal-the total cost escalates to USD 361 billion. Without significant improvements in waste management practices, this figure could nearly double by 2050, reaching an estimated USD 640.3 billion annually. Among municipal solid waste, biowaste accounts for roughly 44 % of the global municipal solid waste, translating to about 840 million tonnes annually. They are widely accessible and economical, offering a cost-effective alternative to traditional treatment materials. Transforming biomass waste into carbon-based materials (e.g., bioaerogels) is a sustainable practice that reduces waste and repurposes it for environmental remediation. This approach not only decreases the volume of waste directed to landfills and mitigates harmful greenhouse gas emissions from decomposition but also aligns with the principles of a circular economy. Furthermore, it supports sustainable development goals by addressing issues such as water scarcity and pollution while promoting waste valorization and resource efficiency. The unique properties of bioaerogels-including their porosity, multi-layered structure, and chemical adaptability-make them highly effective for the remediation of different water pollutants from aquatic bodies. This review article comprehensively delves into multifaceted wastewater remediation strategies -based bioaerogels such as coagulation and flocculation, advanced oxidation processes, membrane filtration, catalytic processes, water disinfection, Oil-water separation, biodegradation, and adsorption. Additionally, it examines different mechanisms of interaction such as surface adsorption, electrostatic interaction, van der Waals forces, ion exchange, surface precipitation, complexation, pore-filling, hydrophobic interactions, and π-π stacking. Moreover, it conducts an integrated techno-economic evaluation to assess their feasibility in wastewater treatment. By valorizing biomass waste, a closed-loop system can be established, where waste is transformed into valuable bioaerogels. This approach not only addresses challenges related to effluent pollution but also generates economic, environmental, and social benefits. Ultimately, the review underscores the transformative potential of bioaerogels in wastewater treatment, emphasizing their crucial role in supporting long-term environmental goals and advancing the principles of resource circularity.

摘要

预计城市固体废物的产生量将从2023年的21亿吨增加到2050年的38亿吨。2020年,全球管理这些废物的直接成本约为2520亿美元。若考虑额外的隐性成本,如因废物处理不当导致的污染、对健康的不利影响和气候变化等成本,总成本将升至3610亿美元。如果废物管理做法没有显著改善,到2050年这个数字可能会几乎翻倍,达到每年约6403亿美元。在城市固体废物中,生物废物约占全球城市固体废物的44%,即每年约8.4亿吨。它们来源广泛且经济实惠,为传统处理材料提供了一种经济高效的替代方案。将生物质废物转化为碳基材料(如生物气凝胶)是一种可持续做法,既能减少废物,又能将其重新用于环境修复。这种方法不仅减少了运往垃圾填埋场的废物量,减轻了分解过程中有害温室气体的排放,还符合循环经济原则。此外,它通过解决水资源短缺和污染等问题,同时促进废物增值和资源效率,支持可持续发展目标。生物气凝胶的独特特性,包括其孔隙率、多层结构和化学适应性,使其对从水体中去除不同的水污染物非常有效。这篇综述文章全面深入地探讨了基于生物气凝胶的多方面废水修复策略,如混凝和絮凝、高级氧化过程、膜过滤、催化过程、水消毒、油水分离、生物降解和吸附。此外,它还研究了不同的相互作用机制,如表面吸附、静电相互作用、范德华力、离子交换、表面沉淀、络合、孔隙填充、疏水相互作用和π-π堆积。此外,它还进行了综合技术经济评估,以评估它们在废水处理中的可行性。通过使生物质废物增值,可以建立一个闭环系统,将废物转化为有价值的生物气凝胶。这种方法不仅解决了与废水污染相关的挑战,还产生了经济、环境和社会效益。最终,该综述强调了生物气凝胶在废水处理中的变革潜力,强调了它们在支持长期环境目标和推进资源循环原则方面的关键作用。

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