Tang Xin, Jiang Hongsheng, Lin Zhengliang, Wang Xuan, Wang Wenliang, Li Guoqiang
State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, 510640, People's Republic of China.
Department of Electronic Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou, 510640, People's Republic of China.
Nanomicro Lett. 2024 Nov 5;17(1):56. doi: 10.1007/s40820-024-01553-8.
van der Waals (vdW) heterostructures constructed by low-dimensional (0D, 1D, and 2D) materials are emerging as one of the most appealing systems in next-generation flexible photodetection. Currently, hand-stacked vdW-type photodetectors are not compatible with large-area-array fabrication and show unimpressive performance in self-powered mode. Herein, vertical 1D GaN nanorods arrays (NRAs)/2D MoS/PEDOT:PSS in wafer scale have been proposed for self-powered flexible photodetectors arrays firstly. The as-integrated device without external bias under weak UV illumination exhibits a competitive responsivity of 1.47 A W and a high detectivity of 1.2 × 10 Jones, as well as a fast response speed of 54/71 µs, thanks to the strong light absorption of GaN NRAs and the efficient photogenerated carrier separation in type-II heterojunction. Notably, the strain-tunable photodetection performances of device have been demonstrated. Impressively, the device at - 0.78% strain and zero bias reveals a significantly enhanced photoresponse with a responsivity of 2.47 A W, a detectivity of 2.6 × 10 Jones, and response times of 40/45 µs, which are superior to the state-of-the-art self-powered flexible photodetectors. This work presents a valuable avenue to prepare tunable vdWs heterostructures for self-powered flexible photodetection, which performs well in flexible sensors.
由低维(0D、1D和2D)材料构建的范德华(vdW)异质结构正成为下一代柔性光探测中最具吸引力的系统之一。目前,手工堆叠的vdW型光电探测器与大面积阵列制造不兼容,并且在自供电模式下表现平平。在此,首次提出了用于自供电柔性光电探测器阵列的晶圆级垂直1D GaN纳米棒阵列(NRAs)/2D MoS/PEDOT:PSS。在弱紫外光照下,集成后的器件在无外部偏压的情况下表现出1.47 A W的竞争响应度、1.2×10琼斯的高探测率以及54/71 μs的快速响应速度,这得益于GaN NRAs的强光吸收和II型异质结中高效的光生载流子分离。值得注意的是,已证明该器件的应变可调光探测性能。令人印象深刻的是,在-0.78%应变和零偏压下的器件显示出显著增强的光响应,响应度为2.47 A W,探测率为2.6×10琼斯,响应时间为40/45 μs,优于目前最先进的自供电柔性光电探测器。这项工作为制备用于自供电柔性光探测的可调vdW异质结构提供了一条有价值的途径,该结构在柔性传感器中表现良好。
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