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用于压光电子效应增强型自供电柔性光电探测器的晶圆级垂直一维氮化镓纳米棒/二维二硫化钼/聚(3,4-乙撑二氧噻吩):聚苯乙烯磺酸盐

Wafer-Scale Vertical 1D GaN Nanorods/2D MoS/PEDOT:PSS for Piezophototronic Effect-Enhanced Self-Powered Flexible Photodetectors.

作者信息

Tang Xin, Jiang Hongsheng, Lin Zhengliang, Wang Xuan, Wang Wenliang, Li Guoqiang

机构信息

State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, 510640, People's Republic of China.

Department of Electronic Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou, 510640, People's Republic of China.

出版信息

Nanomicro Lett. 2024 Nov 5;17(1):56. doi: 10.1007/s40820-024-01553-8.


DOI:10.1007/s40820-024-01553-8
PMID:39497008
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11534966/
Abstract

van der Waals (vdW) heterostructures constructed by low-dimensional (0D, 1D, and 2D) materials are emerging as one of the most appealing systems in next-generation flexible photodetection. Currently, hand-stacked vdW-type photodetectors are not compatible with large-area-array fabrication and show unimpressive performance in self-powered mode. Herein, vertical 1D GaN nanorods arrays (NRAs)/2D MoS/PEDOT:PSS in wafer scale have been proposed for self-powered flexible photodetectors arrays firstly. The as-integrated device without external bias under weak UV illumination exhibits a competitive responsivity of 1.47 A W and a high detectivity of 1.2 × 10 Jones, as well as a fast response speed of 54/71 µs, thanks to the strong light absorption of GaN NRAs and the efficient photogenerated carrier separation in type-II heterojunction. Notably, the strain-tunable photodetection performances of device have been demonstrated. Impressively, the device at - 0.78% strain and zero bias reveals a significantly enhanced photoresponse with a responsivity of 2.47 A W, a detectivity of 2.6 × 10 Jones, and response times of 40/45 µs, which are superior to the state-of-the-art self-powered flexible photodetectors. This work presents a valuable avenue to prepare tunable vdWs heterostructures for self-powered flexible photodetection, which performs well in flexible sensors.

摘要

由低维(0D、1D和2D)材料构建的范德华(vdW)异质结构正成为下一代柔性光探测中最具吸引力的系统之一。目前,手工堆叠的vdW型光电探测器与大面积阵列制造不兼容,并且在自供电模式下表现平平。在此,首次提出了用于自供电柔性光电探测器阵列的晶圆级垂直1D GaN纳米棒阵列(NRAs)/2D MoS/PEDOT:PSS。在弱紫外光照下,集成后的器件在无外部偏压的情况下表现出1.47 A W的竞争响应度、1.2×10琼斯的高探测率以及54/71 μs的快速响应速度,这得益于GaN NRAs的强光吸收和II型异质结中高效的光生载流子分离。值得注意的是,已证明该器件的应变可调光探测性能。令人印象深刻的是,在-0.78%应变和零偏压下的器件显示出显著增强的光响应,响应度为2.47 A W,探测率为2.6×10琼斯,响应时间为40/45 μs,优于目前最先进的自供电柔性光电探测器。这项工作为制备用于自供电柔性光探测的可调vdW异质结构提供了一条有价值的途径,该结构在柔性传感器中表现良好。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/70b7cbcefe1a/40820_2024_1553_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/7ab7b6df1f80/40820_2024_1553_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/9fc3aa73ad84/40820_2024_1553_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/a65411b63c77/40820_2024_1553_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/31bf08a3d335/40820_2024_1553_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/86b80b69cf2a/40820_2024_1553_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/70b7cbcefe1a/40820_2024_1553_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/7ab7b6df1f80/40820_2024_1553_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/9fc3aa73ad84/40820_2024_1553_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/a65411b63c77/40820_2024_1553_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/31bf08a3d335/40820_2024_1553_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/86b80b69cf2a/40820_2024_1553_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2533/11534966/70b7cbcefe1a/40820_2024_1553_Fig6_HTML.jpg

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本文引用的文献

[1]
Large-scale synthesis and exciton dynamics of monolayer MoS on differently doped GaN substrates.

Nanophotonics. 2023-11-22

[2]
Uncooled Mid-Infrared Sensing Enabled by Chip-Integrated Low-Temperature-Grown 2D PdTe Dirac Semimetal.

Nano Lett. 2023-9-13

[3]
Phase-controlled van der Waals growth of wafer-scale 2D MoTe layers for integrated high-sensitivity broadband infrared photodetection.

Light Sci Appl. 2023-1-2

[4]
High performance 1D-2D CuO/MoS photodetectors enhanced by femtosecond laser-induced contact engineering.

Mater Horiz. 2023-2-6

[5]
Charge transfer dynamics and interlayer exciton formation in MoS/VOPc mixed dimensional heterojunction.

J Chem Phys. 2022-11-14

[6]
High-temperature flexible WSe photodetectors with ultrahigh photoresponsivity.

Nat Commun. 2022-7-28

[7]
Fabrication of PdSe/GaN Schottky Junction for Polarization-Sensitive Ultraviolet Photodetection with High Dichroic Ratio.

ACS Nano. 2022-4-26

[8]
Highly Enhanced Photoluminescence of Monolayer MoS in Plasmonic Hybrids with Double-Layer Stacked Ag Nanoparticles.

ACS Appl Mater Interfaces. 2022-3-16

[9]
Vertical 1D/2D Heterojunction Architectures for Self-Powered Photodetection Application: GaN Nanorods Grown on Transition Metal Dichalcogenides.

ACS Nano. 2022-2-22

[10]
Robust Interlayer Exciton in WS/MoSe van der Waals Heterostructure under High Pressure.

Nano Lett. 2021-10-13

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