用于增强光催化降解芥子气模拟物的金属卟啉金属有机框架
Metalloporphyrinic metal-organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant.
作者信息
Quon Alisa S, Manriquez Doroteo, Nguyen Anna, Papazyan Edgar K, Wijeratne Pavithra, An Lun, Qi Long, Tang Matthew J, Ready Austin D, Farha Omar K, Liu Yangyang
机构信息
Department of Chemistry and Biochemistry, California State University, Los Angeles, 5151 State University Drive, Los Angeles, California 90032, USA.
U.S. DOE Ames National Laboratory, Iowa State University, Ames, Iowa 50011, USA.
出版信息
Chem Commun (Camb). 2024 Dec 17;61(1):77-80. doi: 10.1039/d4cc03890h.
Abstract
Four metalloporphyrinic metal-organic frameworks (MOFs) were successfully synthesized and exhibited enhanced activities for the photooxidation of a sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES). Among them, a Sn-porphyrin functionalized 2D MOF, namely CSLA-21-NH(Sn), showed a half-life of 1.5 min for CEES oxidation under blue LED, featuring as one of the fastest photocatalysts for CEES degradation.
摘要
成功合成了四种金属卟啉金属有机框架（MOF），它们对硫芥模拟物2-氯乙基乙基硫醚（CEES）的光氧化表现出增强的活性。其中，一种锡卟啉功能化的二维MOF，即CSLA-21-NH(Sn)，在蓝色发光二极管下对CEES氧化的半衰期为1.5分钟，是CEES降解最快的光催化剂之一。
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