Reinhart Erik D, Studvick Chad M, Billow Brennan S, Odom Aaron L, Popov Ivan A, Boncella James M
Pacific Northwest National Laboratory, Richland, Washington, 99345, United States of America.
Department of Chemistry, The University of Akron, Akron, Ohio, 44325-3601, United States of America.
Chemistry. 2025 Feb 12;31(9):e202403859. doi: 10.1002/chem.202403859. Epub 2024 Dec 2.
Reduction of Cp*(TerN)UI with KC generates (KCp*(TerN)UI), the first example of a trivalent uranium imido, a previously elusive species, which are commonly unstable. Experimental and computational results indicate that the K coordination is responsible for this isolable U(III) monoimido complex.
用KC还原Cp*(TerN)UI生成了(KCp*(TerN)UI)，这是首例三价铀亚胺配合物，此前该物种难以捉摸且通常不稳定。实验和计算结果表明，钾配位作用是这种可分离的U(III)单亚胺配合物得以形成的原因。
