• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

提高用于含油废水处理的膜性能：使用TiO、BiVO、CNT和PVP通过涂覆、共混和接枝方法制备的聚偏氟乙烯复合膜的比较

Enhancing membrane performance for oily wastewater treatment: comparison of PVDF composite membranes prepared by coating, blending, and grafting methods using TiO, BiVO, CNT, and PVP.

作者信息

Santos Erika Nascimben, Fazekas Ákos Ferenc, Fekete Laura, Miklós Tímea, Gyulavári Tamás, Gokulakrishnan Sivasundari Arumugam, Arthanareeswaran Gangasalam, Hodúr Cecilia, László Zsuzsanna, Veréb Gábor

机构信息

Institute of Biosystem Engineering, Faculty of Engineering, University of Szeged, Moszkvai Blvd. 9, HU-6725, Szeged, Hungary.

Doctoral School of Environmental Sciences, Faculty of Science and Informatics, University of Szeged, Aradi Vértanúk Sqr. 1, HU-6720, Szeged, Hungary.

出版信息

Environ Sci Pollut Res Int. 2024 Dec;31(56):64578-64595. doi: 10.1007/s11356-024-35456-3. Epub 2024 Nov 14.

DOI:10.1007/s11356-024-35456-3
PMID:39541027
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11624227/
Abstract

This comparative study investigates the modification of polyvinylidene fluoride (PVDF) membranes with different nanoparticles (TiO or TiO-based composites containing BiVO and/or CNT), using three distinct methods (blending, coating, and grafting) and polyvinylpyrrolidone (PVP). The objective was to enhance the photocatalytic and filtration performance for the separation of oil-in-water emulsions. Regarding the UV activity, the PVDF-TiO/CNT/PVP-coated membrane presented the best performance. Overall, the addition of 2 wt.% CNT to the TiO notably enhanced the photocatalytic activity of the membranes for both UV and visible irradiations. Meanwhile, the presence of 2 wt.% BiVO was beneficial only for photocatalysis under visible light irradiation. Regarding the filtration of the oil-in-water emulsions, 2 wt.% CNT or BiVO addition resulted in the highest fluxes in the series of the PVDF-TiO-grafted membranes. The presence of pore former PVP led to relatively high fluxes and photocatalytic activities for all series. Regarding the modification methods, coated membranes showed the highest photocatalytic efficiency and lowest fluxes. Grafted membranes showed relatively high photocatalytic efficiencies and the best filtration performances.

摘要

这项比较研究使用三种不同方法（共混、涂层和接枝）以及聚乙烯吡咯烷酮（PVP），研究了用不同纳米颗粒（TiO或含BiVO和/或CNT的TiO基复合材料）对聚偏氟乙烯（PVDF）膜进行改性。目的是提高光催化和过滤性能，以分离水包油乳液。关于紫外线活性，PVDF-TiO/CNT/PVP涂层膜表现出最佳性能。总体而言，向TiO中添加2 wt.%的CNT显著提高了膜在紫外线和可见光照射下的光催化活性。同时，2 wt.%的BiVO仅在可见光照射下对光催化有益。关于水包油乳液的过滤，添加2 wt.%的CNT或BiVO导致PVDF-TiO接枝膜系列中的通量最高。致孔剂PVP的存在使所有系列的通量和光催化活性相对较高。关于改性方法，涂层膜显示出最高的光催化效率和最低的通量。接枝膜显示出相对较高的光催化效率和最佳的过滤性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11ec/11624227/2af3d6419e41/11356_2024_35456_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11ec/11624227/8ed641535e64/11356_2024_35456_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11ec/11624227/0ed6981a0505/11356_2024_35456_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11ec/11624227/1abc4048fe20/11356_2024_35456_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11ec/11624227/e1b140e513c9/11356_2024_35456_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11ec/11624227/2af3d6419e41/11356_2024_35456_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11ec/11624227/8ed641535e64/11356_2024_35456_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11ec/11624227/0ed6981a0505/11356_2024_35456_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11ec/11624227/1abc4048fe20/11356_2024_35456_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11ec/11624227/e1b140e513c9/11356_2024_35456_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11ec/11624227/2af3d6419e41/11356_2024_35456_Fig5_HTML.jpg

相似文献

1
Enhancing membrane performance for oily wastewater treatment: comparison of PVDF composite membranes prepared by coating, blending, and grafting methods using TiO, BiVO, CNT, and PVP.提高用于含油废水处理的膜性能：使用TiO、BiVO、CNT和PVP通过涂覆、共混和接枝方法制备的聚偏氟乙烯复合膜的比较
Environ Sci Pollut Res Int. 2024 Dec;31(56):64578-64595. doi: 10.1007/s11356-024-35456-3. Epub 2024 Nov 14.
2
Visible-light-driven photocatalytic PVDF-TiO/CNT/BiVO hybrid nanocomposite ultrafiltration membrane for dairy wastewater treatment.可见光驱动光催化 PVDF-TiO/CNT/BiVO 杂化纳米复合超滤膜用于处理乳制品废水。
Chemosphere. 2022 Nov;307(Pt 1):135589. doi: 10.1016/j.chemosphere.2022.135589. Epub 2022 Jul 5.
3
Fouling mitigation and cleanability of TiO photocatalyst-modified PVDF membranes during ultrafiltration of model oily wastewater with different salt contents.在不同盐含量的模拟含油废水中超滤时，TiO2 光催化剂改性聚偏氟乙烯膜的污染缓解和清洁性能。
Environ Sci Pollut Res Int. 2018 Dec;25(35):34912-34921. doi: 10.1007/s11356-017-0998-7. Epub 2017 Dec 29.
4
Investigation of Photocatalytic PVDF Membranes Containing Inorganic Nanoparticles for Model Dairy Wastewater Treatment.含无机纳米粒子的光催化聚偏氟乙烯膜用于模拟乳品废水处理的研究
Membranes (Basel). 2023 Jul 10;13(7):656. doi: 10.3390/membranes13070656.
5
TiO coated on PVDF membrane for dye wastewater treatment by a photocatalytic membrane.负载于聚偏氟乙烯膜上的二氧化钛用于光催化膜处理染料废水。
Water Sci Technol. 2019 Mar;79(5):958-966. doi: 10.2166/wst.2019.023.
6
TiO-PAA-SiO pearl chain blend modified polyvinylidene fluoride ultrafiltration membrane with excellent oil-water separation, anti fouling performance and durability.TiO-PAA-SiO 核壳珍珠链共混改性聚偏氟乙烯超滤膜具有优异的油水分离、抗污染性能和耐久性。
Environ Technol. 2024 Oct;45(24):5123-5148. doi: 10.1080/09593330.2023.2283804. Epub 2023 Nov 28.
7
Evaluation of self-cleaning performance of the modified g-CN and GO based PVDF membrane toward oil-in-water separation under visible-light.改性 g-CN 和 GO 基 PVDF 膜在可见光下用于油水分离的自清洁性能评价。
Chemosphere. 2019 Sep;230:40-50. doi: 10.1016/j.chemosphere.2019.05.061. Epub 2019 May 11.
8
Outstanding Separation Performance of Oil-in-Water Emulsions with TiO/CNT Nanocomposite-Modified PVDF Membranes.TiO/CNT纳米复合改性聚偏氟乙烯膜对水包油乳液的优异分离性能
Membranes (Basel). 2023 Feb 8;13(2):209. doi: 10.3390/membranes13020209.
9
Statistical Analysis of Synthesis Parameters to Fabricate PVDF/PVP/TiO Membranes via Phase-Inversion with Enhanced Filtration Performance and Photocatalytic Properties.通过相转化法制备具有增强过滤性能和光催化性能的PVDF/PVP/TiO膜的合成参数统计分析
Polymers (Basel). 2021 Dec 29;14(1):113. doi: 10.3390/polym14010113.
10
Intensification of the ultrafiltration of real oil-contaminated (produced) water with pre-ozonation and/or with TiO, TiO/CNT nanomaterial-coated membrane surfaces.强化预臭氧化和/或 TiO、TiO/CNT 纳米材料涂覆膜表面对真实含油（采出）水的超滤。
Environ Sci Pollut Res Int. 2020 Jun;27(18):22195-22205. doi: 10.1007/s11356-020-08047-1. Epub 2020 Feb 14.

本文引用的文献

1
Evaluating the Optimal Oil Concentrations in the Startup Performance of a Membrane Bioreactor Treating Oily Noodle-soup Wastewater.评价膜生物反应器处理含油面汤废水启动性能的最佳油浓度。
J Oleo Sci. 2023;72(3):357-367. doi: 10.5650/jos.ess22360.
2
Hydrogel/β-FeOOH-Coated Poly(vinylidene fluoride) Membranes with Superhydrophilicity/Underwater Superoleophobicity Facilely Fabricated via an Aqueous Approach for Multifunctional Applications.通过水相法简便制备的具有超亲水性/水下超疏油性的水凝胶/β-氢氧化铁包覆聚偏氟乙烯膜用于多功能应用
Polymers (Basel). 2023 Feb 8;15(4):839. doi: 10.3390/polym15040839.
3
Outstanding Separation Performance of Oil-in-Water Emulsions with TiO/CNT Nanocomposite-Modified PVDF Membranes.
TiO/CNT纳米复合改性聚偏氟乙烯膜对水包油乳液的优异分离性能
Membranes (Basel). 2023 Feb 8;13(2):209. doi: 10.3390/membranes13020209.
4
Spraying Fluorinated Silicon Oxide Nanoparticles on CuONPs@CF-PVDF Membrane: A Simple Method to Achieve Superhydrophobic Surfaces and High Flux in Direct Contact Membrane Distillation.在CuONPs@CF-PVDF膜上喷涂氟化二氧化硅纳米颗粒：一种在直接接触膜蒸馏中实现超疏水表面和高通量的简单方法。
Polymers (Basel). 2022 Nov 27;14(23):5164. doi: 10.3390/polym14235164.
5
Superhydrophilic Modification of Polyvinylidene Fluoride Membrane via a Highly Compatible Covalent Organic Framework-COOH/Dopamine-Integrated Hierarchical Assembly Strategy for Oil-Water Separation.通过高度相容的共价有机框架-COOH/多巴胺集成分级组装策略对聚偏氟乙烯膜进行超亲水化改性用于油水分离
ACS Appl Mater Interfaces. 2022 Oct 12;14(40):45880-45892. doi: 10.1021/acsami.2c13402. Epub 2022 Sep 27.
6
Fabrication of a Novel (PVDF/MWCNT/Polypyrrole) Antifouling High Flux Ultrafiltration Membrane for Crude Oil Wastewater Treatment.用于原油废水处理的新型（聚偏氟乙烯/多壁碳纳米管/聚吡咯）抗污染高通量超滤膜的制备
Membranes (Basel). 2022 Jul 30;12(8):751. doi: 10.3390/membranes12080751.
7
Visible-light-driven photocatalytic PVDF-TiO/CNT/BiVO hybrid nanocomposite ultrafiltration membrane for dairy wastewater treatment.可见光驱动光催化 PVDF-TiO/CNT/BiVO 杂化纳米复合超滤膜用于处理乳制品废水。
Chemosphere. 2022 Nov;307(Pt 1):135589. doi: 10.1016/j.chemosphere.2022.135589. Epub 2022 Jul 5.
8
Enhanced Photocatalytic Degradation of Tetracycline and Oxytetracycline Antibiotics by BiVO Photocatalyst under Visible Light and Solar Light Irradiation.BiVO光催化剂在可见光和太阳光照射下对四环素和土霉素抗生素的增强光催化降解作用
Antibiotics (Basel). 2022 Jun 2;11(6):761. doi: 10.3390/antibiotics11060761.
9
A review on organic-inorganic hybrid nanocomposite membranes: a versatile tool to overcome the barriers of forward osmosis.有机-无机杂化纳米复合膜综述：一种克服正向渗透障碍的通用工具。
RSC Adv. 2018 Mar 12;8(18):10040-10056. doi: 10.1039/c7ra12835e. eCollection 2018 Mar 5.
10
Preparation of Nano-TiO-Modified PVDF Membranes with Enhanced Antifouling Behaviors via Phase Inversion: Implications of Nanoparticle Dispersion Status in Casting Solutions.通过相转化法制备具有增强抗污染性能的纳米TiO₂改性聚偏氟乙烯膜：纳米颗粒在铸膜液中的分散状态的影响
Membranes (Basel). 2022 Mar 31;12(4):386. doi: 10.3390/membranes12040386.