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不同塑料的熔积增材制造样品的机械性能随填料百分比和结构的变化

Mechanical properties variation of samples fabricated by fused deposition additive manufacturing as a function of filler percentage and structure for different plastics.

作者信息

Grigoriev Sergey, Nikitin Nikita, Yanushevich Oleg, Krikheli Natella, Khmyrov Roman, Strunevich Daniil, Soloninkin Mihail, Pinargote Nestor Washington Solis, Peretyagin Pavel, Smirnov Anton

机构信息

Spark Plasma Sintering Research Laboratory, Moscow State University of Technology "STANKIN", Vadkovsky per. 1, Moscow, 127055, Russia.

College of New Materials and Nanotechnologies, National University of Science & Technology (MISIS), Leninskii prosp, 4, 119049, Moscow, Russia.

出版信息

Sci Rep. 2024 Nov 16;14(1):28344. doi: 10.1038/s41598-024-79213-5.

Abstract

One of the key factors in manufacturing products by fused deposition molding (FDM) or layer-by-layer printing technology is the material intensity of the product. The task of reducing the amount of material required to manufacture a product without significant loss of mechanical properties is one of the most practically important technological tasks. Material saving in FDM printing of products allows to reduce financial costs and increase the speed of manufacturing of the final product without reducing (or not significantly reducing) the quality properties of the product. In our work it is demonstrated that using Combs filling type and materials of poly lactic acid (PLA) and polyethylene terephthalate glycol (PETG) it is possible to achieve material savings of up to 23% at 50% filling for PLA and 17% at 75% filling for PETG without significant reduction of product strength in comparison with other filling types. Exceptions are PLA samples with 100% fill and Lateral fill. Application of Kruskal-Wallis criterion and Dunn's criterion with Bonferroni multiple comparison correction showed that there were no statistically significant differences within the strength limits of samples made by FDM printing technology from PLA and PETG plastics (p-value = 0.0514), as well as samples with Triangle and Grid filling type (p-value = 1). Based on this result, three groups of samples statistically significantly differing in ultimate strength were identified by methods of hierarchical cluster analysis; in each group (except for group 1, which included samples made of PLA plastic with Lateral filling type and 100% filling), correlation analysis was performed (Spearman correlation was used). The results of the correlation analysis showed a stable average correlation between the percentage of filling, modulus along the secant 0.05-0.2% strain, ultimate strength and strain corresponding to the yield stress. Analysis of the correlation graph showed that the main parameter correlating with all mechanical properties of the specimen is the 0.05-0.2% strain modulus. Based on this conclusion, robust regression equations predicting the 0.05-0.2% strain modulus as a function of the percentage of specimen filling were constructed for the two selected groups. Analysis of the equations showed that in the third group of specimens, the average modulus of 0.05-0.2% strain is more than twice the modulus of 0.05-0.2% strain in the second group. The detected statistical regularities can be explained by the mechanism of strain hardening, the actual value of which depends on the structure of the macrodefect (type of filling), properties and volume of the material (percentage of filling) used in the fabrication of samples using FDM printing technology.

摘要

通过熔融沉积成型(FDM)或逐层打印技术制造产品的关键因素之一是产品的材料强度。在不显著损失机械性能的情况下减少制造产品所需材料量的任务是最具实际重要性的技术任务之一。在FDM打印产品中节省材料可以降低财务成本并提高最终产品的制造速度,同时不降低(或不会显著降低)产品的质量特性。在我们的工作中表明,使用梳状填充类型以及聚乳酸(PLA)和聚对苯二甲酸乙二醇酯(PETG)材料,与其他填充类型相比,对于PLA在50%填充率时可实现高达23%的材料节省,对于PETG在75%填充率时可实现17%的材料节省,且产品强度不会显著降低。例外情况是100%填充的PLA样品和横向填充。应用带有Bonferroni多重比较校正的Kruskal-Wallis检验和Dunn检验表明,由FDM打印技术用PLA和PETG塑料制成的样品强度范围内没有统计学显著差异(p值 = 0.0514),以及三角形和网格填充类型的样品也没有差异(p值 = 1)。基于此结果,通过层次聚类分析方法确定了三组极限强度有统计学显著差异的样品;在每组中(除了第一组,其包括横向填充类型且100%填充的PLA塑料制成的样品)进行了相关性分析(使用Spearman相关性)。相关性分析结果表明,填充百分比、0.05 - 0.2%应变下的割线模量、极限强度以及对应屈服应力的应变之间存在稳定的平均相关性。对相关图的分析表明,与试样所有机械性能相关的主要参数是0.05 - 0.2%应变模量。基于此结论,为两个选定的组构建了预测0.05 - 0.2%应变模量作为试样填充百分比函数的稳健回归方程。对方程的分析表明,在第三组试样中,0.05 - 0.2%应变的平均模量是第二组中0.05 - 0.2%应变模量的两倍多。检测到的统计规律可以通过应变硬化机制来解释,其实际值取决于宏观缺陷的结构(填充类型)、用于使用FDM打印技术制造样品的材料的性能和体积(填充百分比)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c41c/11569163/dd3ffd20bbf7/41598_2024_79213_Fig1_HTML.jpg

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