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采用铜铁氧体磁性纳米颗粒辅助批式吸附法去除合成废水中的镉离子。

Removal of cadmium ions from synthetic wastewater samples by copper ferrite magnetic nanoparticle-assisted batch-type adsorption-based removal strategy.

机构信息

Department of Chemistry, Faculty of Art and Science, Yildiz Technical University, 34220, Istanbul, Turkey.

Chemistry Department, TEBIP Programme, Istanbul University, 34320, Istanbul, Turkey.

出版信息

Environ Monit Assess. 2024 Nov 18;196(12):1210. doi: 10.1007/s10661-024-13408-1.

DOI:10.1007/s10661-024-13408-1
PMID:39556162
Abstract

Industrial activities can release a variety of harmful substances, including organic and inorganic components, into the environment. Inadequate treatment and discharge of these pollutants into aquatic environments might have adverse effects. Cadmium (Cd) is a toxic element found in various environmental sources, both anthropogenic and geogenic, which can contaminate soils and groundwater crucial for providing healthy food and safe drinking water. This study aimed to develop a novel strategy by the help of nano-sized adsorbents to remove cadmium ions from wastewater through batch-type adsorption processes. CuFeO nanoparticles having high magnetic properties were synthesized using a co-precipitation process for the efficient removal of analyte. Characterization of the nanomaterial was performed using field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) analysis. Method effective parameters were systematically optimized through univariate experiments to find proper conditions for the improvement of interaction between the adsorbent and cadmium ions. Removal efficiency (%RE) of Cd was assessed by using synthetic wastewater samples, and the accuracy/practicability of the recommended method proved highly efficient within the linear range of flame atomic absorption spectrophotometry (FAAS). In addition, the Langmuir isotherm model was applied to the experimental data, and the effective adsorption of cadmium from synthetic wastewater by the magnetic CuFeO nanoparticles was proved.

摘要

工业活动会将各种有害物质(包括有机和无机成分)释放到环境中。如果这些污染物未经适当处理就排放到水生环境中,可能会产生不良影响。镉(Cd)是一种在各种环境源(人为和地质)中都存在的有毒元素,它会污染土壤和地下水,而这些是提供健康食品和安全饮用水的关键。本研究旨在通过使用纳米尺寸的吸附剂开发一种新策略,通过批量吸附过程从废水中去除镉离子。使用共沉淀法合成了具有高磁性能的 CuFeO 纳米颗粒,以有效地去除分析物。使用场发射扫描电子显微镜(FE-SEM)、X 射线衍射(XRD)和 Brunauer-Emmett-Teller(BET)分析对纳米材料进行了表征。通过单变量实验系统地优化了方法有效参数,以找到改善吸附剂与镉离子之间相互作用的适当条件。通过使用合成废水样品评估了 Cd 的去除效率(%RE),并证明所推荐方法的准确性/实用性在火焰原子吸收分光光度法(FAAS)的线性范围内非常高效。此外,还应用了 Langmuir 等温模型对实验数据进行了分析,证明了磁性 CuFeO 纳米颗粒从合成废水中有效吸附了镉。

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