Del Olmo Ruben, Tynkevych Olena, Łazińska Magdalena, Syrek Karolina, Durejko Tomasz, Czerwiński Mateusz, Zaraska Leszek, Tiwari Ratnesh, Michalska-Domańska Marta
Institute of Optoelectronics, Military University of Technology, 2 Kaliskiego Str., 00-908 Warsaw, Poland.
Vrije Universiteit Brussel, Department Materials and Chemistry (MACH), Research Group Sustainable Materials engineering (SUME), Vrije Universiteit Brussel (VUB), 1050 Brussels, Belgium.
Rep Prog Phys. 2025 Jan 6;88(2). doi: 10.1088/1361-6633/ad959b.
This review aims to comprehensively and systematically analyze the anodic oxidation process to form nanostructured oxide films on the surface of the most technologically relevant Fe-based alloys and steels. A special emphasis is put on detailed analysis of the mechanisms of the anodic formation of Fe-based nanostructured materials. The effect of anodizing parameters including the type of Fe-alloy, electrolyte composition, potential/current regimes, as well as various post-treatment procedures (including annealing treatment) on the growth, morphology, composition, and properties of the resulting oxide films is discussed in detail. Examples of possible applications of the anodic films grown on Fe-alloys in various fields including photocatalysis, energy storage, sensors, biomedicine, and others are also provided. Finally, current trends, challenges, and perspectives in the anodizing of Fe-alloys are addressed.
本综述旨在全面、系统地分析在技术上最相关的铁基合金和钢表面形成纳米结构氧化膜的阳极氧化过程。特别强调对铁基纳米结构材料阳极形成机制的详细分析。详细讨论了包括铁合金类型、电解质成分、电位/电流制度以及各种后处理程序（包括退火处理）在内的阳极氧化参数对所得氧化膜的生长、形态、成分和性能的影响。还提供了在铁合金上生长的阳极膜在光催化、能量存储、传感器、生物医学等各个领域的可能应用示例。最后，阐述了铁合金阳极氧化的当前趋势、挑战和前景。
