Chen Chen-Xi, Cai Hua-Wen, Sun Xiao-Li, Wan Wen-Ming, Huang Bao-Quan
College of Environmental and Resource Sciences, Engineering Research Center of Polymer Green Recycling of Ministry of Education, Fujian Key Laboratory of Pollution Control & Resource Reuse, Fujian Normal University, Fuzhou, 350007, P. R. China.
Chempluschem. 2025 Feb;90(2):e202400633. doi: 10.1002/cplu.202400633. Epub 2024 Dec 4.
Luminescent polymers have gained considerable research effects in different fields, which are generally prepared by incorporating traditional luminescent moieties. In recent years, non-traditional intrinsic luminescent (NTIL) polymers containing no traditional luminescent moieties have been reported, which have attracted broad attention. This review summarizes recent advances in multicolor NTIL polymers, including stimuli-responsive NTIL polymers, multicolor luminescence of NTIL polymers through polymerization-induced emission strategy or molecular structure modulation, and the positive influence of through-space charge-transfer effect and hydrogen bonding construction strategy on NTIL polymers. This review on NTIL polymers may cause inspirations in different fields.
发光聚合物在不同领域已取得了相当大的研究成果，它们通常是通过引入传统发光基团来制备的。近年来，不含传统发光基团的非传统本征发光（NTIL）聚合物已被报道，这引起了广泛关注。本综述总结了多色NTIL聚合物的最新进展，包括刺激响应性NTIL聚合物、通过聚合诱导发射策略或分子结构调制实现的NTIL聚合物的多色发光，以及空间电荷转移效应和氢键构建策略对NTIL聚合物的积极影响。这篇关于NTIL聚合物的综述可能会在不同领域引发灵感。
