• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

纤维素负载的铂和钯纳米颗粒对烯丙基苯氢化反应的催化活性

Catalytic Activity of Cellulose-Supported Platinum and Palladium Nanoparticles for Allylbenzene Hydrogenation.

作者信息

Thiel Tabea Angela, Parapat Riny Yolandha, Schroeter Michael, Schwarze Michael

机构信息

Department of Chemistry, Technische Universität Berlin, TC8, Straße des 17. Juni 124, 10623, Berlin, Germany.

Leibniz Institute for Catalysis, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.

出版信息

Chemistry. 2025 Jan 9;31(2):e202402952. doi: 10.1002/chem.202402952. Epub 2024 Dec 12.

DOI:10.1002/chem.202402952
PMID:39587834
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11724257/
Abstract

Platinum and palladium nanoparticles were successfully deposited on tunicate cellulose via the photodeposition or microemulsion deposition method. Evenly distributed, small and narrow-sized particles in the range of 2-3 nm were obtained for microemulsion-prepared cellulose catalysts. The photodeposition method led to larger particle sizes, broader size distribution, and occasional agglomerations. The catalysts were tested in the allylbenzene hydrogenation reaction at room temperature and the results were compared to commercially available catalysts. Because of smaller particles, both microemulsion-prepared catalysts and photodeposited ones show better activity than commercial catalysts. Even platinum and palladium nanoparticles were active for the hydrogenation, only cellulose-supported platinum nanoparticles showed good stability. For palladium nanoparticles, stronger leaching from the surface of cellulose was observed. Cellulose-supported catalysts were recycled, and reusability is comparable to commercial catalysts. Therefore, cellulose could be used as an alternative catalyst support.

摘要

通过光沉积或微乳液沉积法成功地将铂和钯纳米颗粒沉积在被囊动物纤维素上。对于微乳液制备的纤维素催化剂，获得了均匀分布、尺寸在2 - 3纳米范围内的小且窄尺寸的颗粒。光沉积法导致颗粒尺寸更大、尺寸分布更宽且偶尔会出现团聚。在室温下对这些催化剂进行烯丙基苯氢化反应测试，并将结果与市售催化剂进行比较。由于颗粒较小，微乳液制备的催化剂和光沉积催化剂都比商业催化剂表现出更好的活性。即使铂和钯纳米颗粒对氢化反应有活性，但只有纤维素负载的铂纳米颗粒表现出良好的稳定性。对于钯纳米颗粒，观察到从纤维素表面有更强的浸出。纤维素负载的催化剂被回收利用，其可重复使用性与商业催化剂相当。因此，纤维素可作为替代催化剂载体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/d258db59b062/CHEM-31-e202402952-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/7587e99263a1/CHEM-31-e202402952-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/801b6ff05358/CHEM-31-e202402952-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/a4cc279e247c/CHEM-31-e202402952-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/c936ed04a09d/CHEM-31-e202402952-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/4b473b4ace97/CHEM-31-e202402952-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/dbdaae8da196/CHEM-31-e202402952-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/6e0e17c34fda/CHEM-31-e202402952-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/93ee70a06e2a/CHEM-31-e202402952-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/6ffe7695ea9e/CHEM-31-e202402952-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/d258db59b062/CHEM-31-e202402952-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/7587e99263a1/CHEM-31-e202402952-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/801b6ff05358/CHEM-31-e202402952-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/a4cc279e247c/CHEM-31-e202402952-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/c936ed04a09d/CHEM-31-e202402952-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/4b473b4ace97/CHEM-31-e202402952-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/dbdaae8da196/CHEM-31-e202402952-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/6e0e17c34fda/CHEM-31-e202402952-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/93ee70a06e2a/CHEM-31-e202402952-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/6ffe7695ea9e/CHEM-31-e202402952-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b18/11724257/d258db59b062/CHEM-31-e202402952-g003.jpg

相似文献

1
Catalytic Activity of Cellulose-Supported Platinum and Palladium Nanoparticles for Allylbenzene Hydrogenation.纤维素负载的铂和钯纳米颗粒对烯丙基苯氢化反应的催化活性
Chemistry. 2025 Jan 9;31(2):e202402952. doi: 10.1002/chem.202402952. Epub 2024 Dec 12.
2
Kinetic investigation of -nitrophenol reduction with photodeposited platinum nanoparticles onto tunicate cellulose.用光沉积在被囊类纤维素上的铂纳米颗粒还原对硝基苯酚的动力学研究。
RSC Adv. 2022 Oct 28;12(48):30860-30870. doi: 10.1039/d2ra05507d. eCollection 2022 Oct 27.
3
Structure and catalytic properties of nanosized alumina supported platinum and palladium particles synthesized by reaction in microemulsion.通过微乳液中的反应合成的纳米氧化铝负载铂和钯颗粒的结构及催化性能
J Colloid Interface Sci. 2003 Dec 15;268(2):348-56. doi: 10.1016/j.jcis.2003.07.041.
4
Development of Nickel- and Magnetite-Promoted Carbonized Cellulose Bead-Supported Bimetallic Pd-Pt Catalysts for Hydrogenation of Chlorate Ions in Aqueous Solution.发展镍和磁铁矿促进的碳化纤维素珠载双金属 Pd-Pt 催化剂用于水溶液中氯酸根离子的加氢。
Int J Mol Sci. 2021 Oct 31;22(21):11846. doi: 10.3390/ijms222111846.
5
Palladium Nanoparticles Supported on Cellulosic Paper as Multifunctional Catalyst for Coupling and Hydrogenation Reactions.负载于纤维素纸上的钯纳米颗粒作为用于偶联和加氢反应的多功能催化剂。
Chem Asian J. 2022 Feb 1;17(3):e202101195. doi: 10.1002/asia.202101195. Epub 2021 Dec 30.
6
Effect of the supports on catalytic activity of Pd catalysts for liquid-phase hydrodechlorination/hydrogenation reaction.载体对钯催化剂在液相加氢脱氯/加氢反应中催化活性的影响。
Environ Technol. 2019 May;40(12):1615-1623. doi: 10.1080/09593330.2018.1426645. Epub 2018 Jan 25.
7
Quasi-homogeneous hydrogenation with platinum and palladium nanoparticles stabilized by dendritic core-multishell architectures.树枝状核壳结构稳定的铂和钯纳米粒子的准均相加氢。
Langmuir. 2011 May 17;27(10):6511-8. doi: 10.1021/la200316b. Epub 2011 Apr 13.
8
Highly efficient and stable catalysts-covalent organic framework-supported palladium particles for 4-nitrophenol catalytic hydrogenation.用于4-硝基苯酚催化加氢的高效稳定催化剂——共价有机框架负载钯颗粒
Environ Res. 2022 Nov;214(Pt 4):114027. doi: 10.1016/j.envres.2022.114027. Epub 2022 Aug 18.
9
Amine Functionalization Leads to Enhanced Performance for Nickel- and Cobalt-Ferrite-Supported Palladium Catalysts in Nitrobenzene Hydrogenation.胺功能化导致负载在镍铁氧体和钴铁氧体上的钯催化剂在硝基苯加氢反应中的性能得到增强。
Int J Mol Sci. 2023 Aug 28;24(17):13347. doi: 10.3390/ijms241713347.
10
Pt, Rh and Pt-Rh nanoparticles on modified single-walled carbon nanotubes for hydrogenation of benzene at room temperature.用于室温下苯加氢反应的修饰单壁碳纳米管负载的铂、铑及铂-铑纳米颗粒。
J Nanosci Nanotechnol. 2011 Oct;11(10):8580-5. doi: 10.1166/jnn.2011.4966.

本文引用的文献

1
Efficient preparation of nanocatalysts. Case study: green synthesis of supported Pt nanoparticles by using microemulsions and mangosteen peel extract.纳米催化剂的高效制备。案例研究：利用微乳液和山竹果皮提取物绿色合成负载型铂纳米颗粒。
RSC Adv. 2022 Nov 30;12(53):34346-34358. doi: 10.1039/d2ra04134k. eCollection 2022 Nov 29.
2
Kinetic investigation of -nitrophenol reduction with photodeposited platinum nanoparticles onto tunicate cellulose.用光沉积在被囊类纤维素上的铂纳米颗粒还原对硝基苯酚的动力学研究。
RSC Adv. 2022 Oct 28;12(48):30860-30870. doi: 10.1039/d2ra05507d. eCollection 2022 Oct 27.
3
Enhanced colloidal stability and antibacterial performance of silver nanoparticles/cellulose nanocrystal hybrids.
银纳米颗粒/纤维素纳米晶杂化物的胶体稳定性和抗菌性能增强
J Mater Chem B. 2015 Jan 28;3(4):603-611. doi: 10.1039/c4tb01647e. Epub 2014 Nov 27.
4
Facile synthesis of palladium and gold nanoparticles by using dialdehyde nanocellulose as template and reducing agent.利用二醛纳米纤维素作为模板和还原剂，通过简便的方法合成钯和金纳米粒子。
Carbohydr Polym. 2018 Apr 15;186:132-139. doi: 10.1016/j.carbpol.2018.01.048.
5
Cellulose Sponge Supported Palladium Nanoparticles as Recyclable Cross-Coupling Catalysts.纤维素海绵负载钯纳米粒子作为可回收交叉偶联催化剂。
ACS Appl Mater Interfaces. 2017 May 24;9(20):17155-17162. doi: 10.1021/acsami.7b03600. Epub 2017 May 15.
6
Cellulose Nanocrystals as Chiral Inducers: Enantioselective Catalysis and Transmission Electron Microscopy 3D Characterization.纤维素纳米晶作为手性诱导剂：手性催化和透射电子显微镜 3D 表征。
J Am Chem Soc. 2015 May 20;137(19):6124-7. doi: 10.1021/jacs.5b02034. Epub 2015 May 5.
7
Catalytic reduction of p-nitrophenol by using platinum nanoparticles stabilised by guar gum.用瓜尔胶稳定的铂纳米粒子催化还原对硝基苯酚。
Carbohydr Polym. 2014 Nov 26;113:525-31. doi: 10.1016/j.carbpol.2014.07.047. Epub 2014 Jul 28.
8
A(3)-Coupling catalyzed by robust Au nanoparticles covalently bonded to HS-functionalized cellulose nanocrystalline films.通过与 HS 功能化纤维素纳米晶体薄膜共价键合的坚固金纳米粒子进行 A(3)-偶联催化。
Beilstein J Org Chem. 2013 Jul 10;9:1388-96. doi: 10.3762/bjoc.9.155. eCollection 2013.
9
Particle shape optimization by changing from an isotropic to an anisotropic nanostructure: preparation of highly active and stable supported Pt catalysts in microemulsions.通过改变各向同性纳米结构为各向异性纳米结构来优化颗粒形状：在微乳液中制备高活性和稳定的负载型 Pt 催化剂。
Nanoscale. 2013 Jan 21;5(2):796-805. doi: 10.1039/c2nr32122j. Epub 2012 Dec 12.
10
Catalysis using gold nanoparticles decorated on nanocrystalline cellulose.使用负载在纳米晶纤维素上的金纳米粒子进行催化。
Nanoscale. 2012 Feb 7;4(3):997-1002. doi: 10.1039/c2nr11558a. Epub 2012 Jan 5.