Zuber Julian, Pickl Thomas, Heidecker Alexandra A, Baron Marco, Jandl Christian, Pöthig Alexander
Catalysis Research Center & Department of Chemistry, Technische Universität München, Ernst-Otto-Fischer Str. 1, 85748 Garching bei München, Germany.
Dipartimento di Scienze Chimiche, Università degli Studi di Padova, via Marzolo 1, 35131 Padova, Italy.
Dalton Trans. 2024 Dec 10;53(48):19116-19120. doi: 10.1039/d4dt02953d.
We report rim-brominated pillarplexes, new examples of functionalised supramolecular organometallic complexes (SOCs). The bromide atoms can be introduced to the established pristine ligand precursor, demonstrating late-stage diversification of our ligand platform. SC-XRD/ED-derived crystal structures of precursor and pillarplex salts are reported along with competitive assembly experiments of the Ag(I) pillarplex, showing narcissistic self-sorting behavior.
我们报道了边缘溴化的柱状配合物，这是功能化超分子有机金属配合物（SOCs）的新实例。溴原子可以引入到已有的原始配体前体中，证明了我们配体平台的后期多样化。报道了前体和柱状配合物盐的SC-XRD/ED衍生晶体结构以及Ag(I)柱状配合物的竞争性组装实验，显示出自恋自分类行为。
