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钙钛矿发光体的光物理:从整体到单粒子

The Photophysics of Perovskite Emitters: from Ensemble to Single Particle.

作者信息

Feng Minjun, Sum Tze Chien

机构信息

Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore, 637371, Singapore.

出版信息

Adv Mater. 2025 Jun;37(25):e2413836. doi: 10.1002/adma.202413836. Epub 2024 Nov 26.

DOI:10.1002/adma.202413836
PMID:39600041
Abstract

Halide perovskite emitters are a groundbreaking class of optoelectronic materials possessing remarkable photophysical properties for diverse applications. In perovskite light emitting devices, they have achieved external quantum efficiencies exceeding 28%, showcasing their potential for next-generation solid-state lighting and ultra high definition displays. Furthermore, the demonstration of room temperature continuous-wave perovskite lasing underscores their potential for integrated optoelectronics. Of late, perovskite emitters are also found to exhibit desirable single-photon emission characteristics as well as superfluorescence or superradiance phenomena for quantum optics. With progressive advances in synthesis, surface engineering, and encapsulation, halide perovskite emitters are poised to become key components in quantum optical technologies. Understanding the underpinning photophysical mechanisms is crucial for engineering these novel emergent quantum materials. This review aims to provide a condensed overview of the current state of halide perovskite emitter research covering both established and fledging applications, distill the underlying mechanisms, and offer insights into future directions for this rapidly evolving field.

摘要

卤化物钙钛矿发光体是一类具有开创性的光电子材料,具有卓越的光物理性质,可用于多种应用。在钙钛矿发光器件中,它们的外量子效率已超过28%,展现出其在下一代固态照明和超高清显示方面的潜力。此外,室温连续波钙钛矿激光发射的演示突出了它们在集成光电子学方面的潜力。最近,还发现钙钛矿发光体表现出理想的单光子发射特性以及用于量子光学的超荧光或超辐射现象。随着合成、表面工程和封装技术的不断进步,卤化物钙钛矿发光体有望成为量子光学技术的关键组件。理解其基础光物理机制对于设计这些新型的新兴量子材料至关重要。本综述旨在简要概述卤化物钙钛矿发光体研究的现状,涵盖已成熟和新兴的应用,提炼其潜在机制,并为这个快速发展的领域提供未来方向的见解。

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