Li Ting, Guan Laiyin, Zeng Mingwan, Li Tongtong, Lei Shuhui, Tang Xiaohan, Pan Yixuan, Li Shasha, Zhou Man, Yuan Xiangyang, Zhang Zhiqing, Wu Hejun
College of Food Science, Sichuan Agricultural University, No.46, Xin Kang Road, Ya'an, Sichuan Province 625014, PR China.
College of Science, Sichuan Agricultural University, No.46, Xin Kang Road, Ya'an, Sichuan Province 625014, PR China.
Int J Biol Macromol. 2025 Jan;284(Pt 1):138091. doi: 10.1016/j.ijbiomac.2024.138091. Epub 2024 Nov 26.
In this study, various levels (0 %-30 % w/w, based on corn starch) of Rosa roxburghii Tratt fruit pomace (RRTP) were used as antioxidant fillers to develop corn starch (CS)-based bioactive films via the extrusion compression molding technique. The results showed that incorporating RRTP into CS could remarkably improve the barrier, mechanical and antioxidant properties of the films compared to pure CS film. In particular, the composite film containing 30 % RRTP had the lowest water vapor permeability and oxygen permeability of 2.94 × 10 g·m·m·s·Pa and 0.87 × 10 kg·m·m·s·Pa, respectively, together with the highest tensile strength of 3.41 MPa and the strongest DPPH scavenging activity of 88.59 %. LCMS analysis confirmed that RRTP contained many phenolic compounds, which conferred high antioxidant activity to the composite films. Additionally, FTIR analyses demonstrated the formation of hydrogen bonds between CS and RRTP, along with good compatibility as confirmed by XRD and SEM. More importantly, the mushrooms packaged in the CS/30%RRTP film maintained optimal appearance and freshness after 12 days at 4 °C, demonstrating the promising role as antioxidant active packaging for food, following new trends for functional packaging.
在本研究中,采用不同含量(基于玉米淀粉,0%-30% w/w)的刺梨果渣(RRTP)作为抗氧化填充剂,通过挤出压缩成型技术制备了基于玉米淀粉(CS)的生物活性薄膜。结果表明,与纯CS薄膜相比,将RRTP加入CS中可显著提高薄膜的阻隔性、机械性能和抗氧化性能。特别是,含有30% RRTP的复合薄膜具有最低的水蒸气透过率和氧气透过率,分别为2.94×10 g·m·m·s·Pa和0.87×10 kg·m·m·s·Pa,同时具有最高的拉伸强度3.41 MPa和最强的DPPH清除活性88.59%。液相色谱-质谱联用分析证实RRTP含有许多酚类化合物,这赋予了复合薄膜较高的抗氧化活性。此外,傅里叶变换红外光谱分析表明CS和RRTP之间形成了氢键,X射线衍射和扫描电子显微镜也证实了它们具有良好的相容性。更重要的是,用CS/30%RRTP薄膜包装的蘑菇在4℃下保存12天后仍保持最佳外观和新鲜度,这表明其作为食品抗氧化活性包装具有广阔前景,符合功能性包装的新趋势。