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后过渡金属二硫属化物SnS纳米花/PVDF复合材料:一种智能可穿戴自供电机械传感器。

Post-Transition Metal Dichalcogenide SnS Nanoflower/PVDF Composite: A Smart Wearable Self-Powered Mechanosensor.

作者信息

Maity Sourav, Kar Epsita, Sen Shrabanee

机构信息

Functional Materials and Devices Division, CSIR- Central Glass and Ceramic Research Institute, Kolkata 700032, West Bengal, India.

Department of Education in Science and Mathematics, Regional Institute of Education-Mysuru, Mysore 570006, Karnataka, India.

出版信息

ACS Appl Mater Interfaces. 2024 Dec 11;16(49):68294-68305. doi: 10.1021/acsami.4c14400. Epub 2024 Nov 28.

Abstract

The escalating demand for wearables has led to a surge in the development of portable and flexible electronics. Consequently, exploring different materials for the efficient design of the device has become an inevitable aspect of this particular research area. Therefore, in this work, we present post-transition metal dichalcogenide tin disulfide (SnS) nanoflowers, to effectively engineer the polyvinylidene fluoride (PVDF) functional layer, which serves as the heart of the device. These hydrothermally grown SnS nanoflowers can significantly nurture the physiochemical properties of the PVDF matrix. Consequently, the assembled optimized device is capable of generating an output voltage of 60 ± 4 V, with an output current of 8 ± 0.4 μA, while maintaining a good output power density of 87.11 μW·cm. The device successfully harvested mechanical energies from several biomechanical movements including finger, elbow, neck, and wrist bending. Furthermore, the optimized device demonstrated a high efficiency in static and dynamic pressure sensing. This utilization of post-transition metal dichalcogenides paves the way for groundbreaking improvements in the fields of biomechanical energy harvesting and static and dynamic pressure sensing.

摘要

对可穿戴设备不断增长的需求推动了便携式和柔性电子产品的快速发展。因此,探索用于高效设计此类设备的不同材料已成为这一特定研究领域不可避免的一个方面。所以,在这项工作中,我们展示了后过渡金属二硫属化物二硫化锡(SnS)纳米花,用于有效设计作为设备核心的聚偏氟乙烯(PVDF)功能层。这些通过水热法生长的SnS纳米花能够显著改善PVDF基体的物理化学性质。因此,组装好的优化设备能够产生60±4V的输出电压,输出电流为8±0.4μA,同时保持87.11μW·cm的良好输出功率密度。该设备成功地从包括手指、肘部、颈部和手腕弯曲在内的多种生物力学运动中收集机械能。此外,优化后的设备在静态和动态压力传感方面表现出高效性。后过渡金属二硫属化物的这种应用为生物机械能收集以及静态和动态压力传感领域带来突破性改进铺平了道路。

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