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利用生物质中的芳烃形成碳-碳键。

Carbon-carbon bond formation using aromatics from biomass.

作者信息

Dunås Petter, Paterson Andrew J, Lewis Simon E, Kann Nina

机构信息

Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-41296 Göteborg, Sweden.

Department of Chemistry, University of Bath, Convocation Avenue, Bath BA2 7AY, UK.

出版信息

Chem Commun (Camb). 2024 Dec 12;60(100):14885-14895. doi: 10.1039/d4cc05664g.

DOI:10.1039/d4cc05664g
PMID:39611735
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11606386/
Abstract

The transition to a circular economy requires that we adapt currently used chemical processes to the structurally diverse and often highly oxygenated precursors that are accessible from biomass. In this review, we highlight different examples of carbon-carbon bond formation using aromatics derived from bio-based sources, reported during 2015-2024. Examples of sustainable biomass building blocks include heterocycles such as furfural and hydroxymethylfurfural, obtained from carbohydrates, as well as lignin-based aromatics such as vanillin and eugenol. These have subsequently been applied in a variety of different types of carbon-carbon bond formation, including more classical methods such as aldol condensation and Morita-Baylis-Hillman reactions, but also employing transition metal catalysis, electrochemistry or photochemistry to create new C-C bonds.

摘要

向循环经济的转变要求我们使当前使用的化学过程适应从生物质中获取的结构多样且通常高度氧化的前体。在本综述中，我们重点介绍了2015年至2024年期间报道的使用源自生物基来源的芳烃形成碳 - 碳键的不同实例。可持续生物质构建块的实例包括从碳水化合物中获得的杂环，如糠醛和羟甲基糠醛，以及基于木质素的芳烃，如香草醛和丁香酚。这些随后被应用于各种不同类型的碳 - 碳键形成反应中，包括更经典的方法，如羟醛缩合和森田 - 贝利斯 - 希尔曼反应，同时也采用过渡金属催化、电化学或光化学来形成新的碳 - 碳键。

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