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基于生物的尼龙56/棉混纺织物用还原染料的优化单浴染色:机理见解与工艺改进

Optimized single-bath dyeing of bio-based nylon 56/cotton blends with vat dyes: Mechanistic insights and process enhancements.

作者信息

Hao Xin-Hui, Wang Qian, Guo Fei, Zhou Zi-Ming, Zhang Xue-Qi, Liu Liu, Wang Mei-Hui, Wang Zhen, Hao Xin-Min, Yi Chang-Hai

机构信息

National Engineering Laboratory for Advanced Yarn and Fabric Formation and Clean Production, Technology Institute, Wuhan Textile University, Wuhan, Hubei 430200, China.

Systems Engineering Institute, Academy of Military Science, Beijing 100010, China.

出版信息

Int J Biol Macromol. 2025 Jan;284(Pt 2):138157. doi: 10.1016/j.ijbiomac.2024.138157. Epub 2024 Nov 27.

Abstract

Nylon 56/cotton (N/C) blended fabrics have excellent durability and can cater to various clothing needs. However, the quality and value of textile garments are significantly influenced by the dyeing process. Due to variations in the structure and characteristics of nylon 56 and cotton fibers in blended fabrics, achieving consistent coloration is challenging, resulting in noticeable color discrepancies. To tackle these issues, this study focused on dyeing nylon 56/cotton blended fabrics in a single bath using vat dyes. The three primary colors of the vat dyes were selected to be suitable for these fabrics. Subsequently, the study explored the impact of different factors on color consistency and optimized the dyeing process conditions using response surface methodology. The findings revealed that fabrics dyed using the optimized process exhibited vibrant colors, uniformity, and excellent colorfastness to soaping and rubbing, surpassing standard requirements. Furthermore, the study delved into the dyeing mechanism of nylon 56/cotton blended fabrics, analyzing the kinetic and thermodynamic properties of dye adsorption on fibers. This analysis aims to provide a theoretical foundation for developing a rational dyeing process and offer guidance for practical production.

摘要

尼龙56/棉(N/C)混纺织物具有出色的耐用性,能够满足各种服装需求。然而,纺织服装的质量和价值受到染色过程的显著影响。由于混纺织物中尼龙56和棉纤维的结构和特性存在差异,实现均匀染色具有挑战性,会导致明显的颜色差异。为了解决这些问题,本研究聚焦于使用还原染料在同一浴中对尼龙56/棉混纺织物进行染色。选择了适合这些织物的三种还原染料原色。随后,该研究探讨了不同因素对颜色一致性的影响,并使用响应面法优化了染色工艺条件。研究结果表明,采用优化工艺染色的织物呈现出鲜艳的颜色、均匀性以及出色的皂洗和摩擦色牢度,超过了标准要求。此外,该研究深入探讨了尼龙56/棉混纺织物的染色机理,分析了染料在纤维上吸附的动力学和热力学性质。这一分析旨在为开发合理的染色工艺提供理论基础,并为实际生产提供指导。

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