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使用直接放电电脉冲从碳纤维增强聚合物中高效回收碳纤维。

Efficient recovery of carbon fibers from carbon fiber-reinforced polymers using direct discharge electrical pulses.

作者信息

Tokoro Chiharu, Sato Keita, Inutsuka Manabu, Koita Taketoshi

机构信息

Department of Creative Science and Engineering, Waseda University, Tokyo, 1698555, Japan.

Faculty of Engineering, The University of Tokyo, Tokyo, 1138656, Japan.

出版信息

Sci Rep. 2024 Nov 30;14(1):29762. doi: 10.1038/s41598-024-76955-0.

Abstract

Carbon fiber-reinforced polymers (CFRPs) are lightweight, high-strength composite materials that are widely used in various industries. However, recycling CFRPs remains a significant challenge because of the difficulty in separating carbon fibers (CFs) from the polymer matrix. This study compares two electrical pulse methods, namely direct discharge (DD) and electrohydraulic fragmentation (EHF), for the energy-efficient and precise recovery of CFs from CFRPs. The DD method involves the direct application of high-voltage pulses to the CFRPs, leveraging the Joule heat generation, thermal stress generation, and expansion force caused by plasma generation. In contrast, EHF is based on intensive shockwave impulses generated by high-voltage discharge plasmas along the interfaces of different materials. We examined the physical properties of the recovered CFs, namely their length, tensile strength, resin adhesion, and structural degradation, as well as the energy efficiency of the two methods in terms of CF separation. The results showed that DD is more effective for CF recovery, considering the preservation of long fibers with high strength and the separation of individual fibers without residual resin on the surface.

摘要

碳纤维增强聚合物(CFRPs)是一种轻质、高强度的复合材料,广泛应用于各个行业。然而,由于难以将碳纤维(CFs)与聚合物基体分离,回收CFRPs仍然是一项重大挑战。本研究比较了两种电脉冲方法,即直接放电(DD)和电液破碎(EHF),用于从CFRPs中高效、精确地回收CFs。DD方法是将高压脉冲直接施加到CFRPs上,利用焦耳热产生、热应力产生以及等离子体产生引起的膨胀力。相比之下,EHF基于高压放电等离子体沿不同材料界面产生的强烈冲击波脉冲。我们研究了回收CFs的物理性能,即其长度、拉伸强度、树脂附着力和结构降解,以及两种方法在CF分离方面的能量效率。结果表明,考虑到保留高强度的长纤维以及分离表面无残留树脂的单根纤维,DD在CF回收方面更有效。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a2d/11607455/94d4929f7031/41598_2024_76955_Fig1_HTML.jpg

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