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多酚-壳聚糖共轭物-丁香酚精油微胶囊的制备、表征及其对樱桃番茄贮藏性能的影响

Preparation and characterization of polyphenol-chitosan conjugate-eugenol essential oil microcapsule and its effect on storage behavior of cherry tomato.

作者信息

Yu Xiaohong, Hu Erhu, Liu Fengyi, Zhang Yan, Li Wangwang, Lyu Yongmei, Li Fengwei, Wang Dujun, Jin Wenbin

机构信息

School of Marine and Bioengineering, Yancheng Institute of Technology, Yancheng, P. R. China.

出版信息

J Food Sci. 2024 Dec;89(12):9577-9594. doi: 10.1111/1750-3841.17524. Epub 2024 Dec 1.

DOI:10.1111/1750-3841.17524
PMID:39617749
Abstract

Given the high volatility, low water solubility, and oxidative sensitivity of essential oils, this study synthesized microcapsules of essential oil (EEO) (quercetin-chitosan-EEO [QE-CS-EEO]) using a QE-CS graft copolymer as the wall material and EEO as the core material. Research findings indicate that QE-CS exhibits superior in vitro antioxidant activity, with scavenging abilities for 2,2-diphenyl-1-picrylhydrazyl and 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) ABTS+ radicals being 58.71% and 77.03% greater than those of CS, respectively, thereby providing more effective protection for the essential oil. In comparison to CS essential oil, microcapsules (CS-EEO), QE-CS-EEO demonstrated an 18.65% increase in EEO encapsulation efficiency, achieving a total encapsulation efficiency of 41.29%. Based on these results, various edible coating solutions were formulated, including Control, E1 (1% CS), E2 (0.5% CS + 0.5% CS-EEO), E3 (0.5% CS + 0.5% QE-CS-EEO), and E4 (1% EEO), to extend the shelf life of cherry tomatoes. Notably, cherry tomatoes treated with the E3 formulation maintained superior freshness indicators, exhibiting an extended shelf life of approximately 9-12 days compared to the control group. This study aims to explore a novel microcapsule wall material and provide a strategy for extending the shelf life of fruits and vegetables, thereby minimizing food waste.

摘要

鉴于精油具有高挥发性、低水溶性和氧化敏感性,本研究以槲皮素-壳聚糖接枝共聚物为壁材、精油为芯材,合成了精油微胶囊(EEO)(槲皮素-壳聚糖-EEO [QE-CS-EEO])。研究结果表明,QE-CS表现出优异的体外抗氧化活性,对2,2-二苯基-1-苦基肼和2,2'-偶氮二异丁基脒二盐酸盐(ABTS+)自由基的清除能力分别比壳聚糖(CS)高58.71%和77.03%,从而为精油提供了更有效的保护。与CS精油微胶囊(CS-EEO)相比,QE-CS-EEO的EEO包封效率提高了18.65%,总包封效率达到41.29%。基于这些结果,配制了各种可食用包衣溶液,包括对照组、E1(1% CS)、E2(0.5% CS + 0.5% CS-EEO)、E3(0.5% CS + 0.5% QE-CS-EEO)和E4(1% EEO),以延长樱桃番茄的货架期。值得注意的是,用E3配方处理的樱桃番茄保持了优异的新鲜度指标,与对照组相比,货架期延长了约9 - 12天。本研究旨在探索一种新型微胶囊壁材,并提供一种延长水果和蔬菜货架期的策略,从而最大限度地减少食物浪费。

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