Moiré Exciton Polaron Engineering via twisted hBN.

Twisted hexagonal boron nitride (thBN) exhibits ferroelectricity due to moiré superlattices with AB/BA domains. These domains possess electric dipoles, leading to a periodic electrostatic potential that can be imprinted onto other materials placed in its proximity. Here we demonstrate the remote imprinting of moiré patterns from thBN onto monolayer MoSe and investigate the changes in the exciton properties. We confirm the imprinted moiré patterns on monolayer MoSe using Kelvin probe force microscopy (KPFM) and hyperspectral photoluminescence (PL) mapping. By creating a large ferroelectric domain (∼8.7 μm), we achieve unprecedented potential modulation (∼387 ± 52 meV). We observe the formation of exciton-polarons by the ferroelectric moiré domains and investigate the optical property changes induced by the moiré pattern in monolayer MoSe by varying the moiré domain size down to ∼110 nm. Our findings highlight the potential of thBN as a platform for controlling the properties of 2D materials for optoelectronic and valleytronic applications.