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联苯菊酯的环境归宿:对其土壤吸附和降解研究的洞察

Bifenthrin's Environmental Fate: An Insight Into Its Soil Sorption and Degradation Studies.

作者信息

Al-Hawadi Jehad S, Majid Sara, Ahmad Khuram Shahzad, Eldesoky Gaber E, Ashraf Ghulam Abbas

机构信息

Faculty of Science, Zarqa University, Zarqa 13110, Jordan.

Materials and Environmental Chemistry Lab, Lab-E21, Department of Environmental Sciences, Fatima Jinnah Women University, Rawalpindi, Pakistan.

出版信息

J Anal Methods Chem. 2024 Nov 25;2024:8868954. doi: 10.1155/jamc/8868954. eCollection 2024.

Abstract

To fully comprehend each pesticide's behavior and interactions with soil and the environment, a thorough and nuanced analysis of each one is thought necessary. In this study, 10 randomly selected heterogeneous soil samples, each with distinct characteristics, were subjected to sorption trials as well as disintegration tests using biodegradation, hydrolysis, and photolysis. For sorption tests, the batch equilibrium approach was used, which revealed a dependence on the soils' physicochemical characteristics. Bifenthrin's distribution coefficient (K ) varied from 7.27 to 25.89 μg·ml, with values varying from 0.92 to 0.99. Each soil physicochemical characteristic was associated with the various sorptive outcomes, which suggested an exothermic adsorptive reaction based on the negative thermodynamic values. The hydrolysis, soil-induced biodegradation, and photolysis processes had the shortest half-lives of bifenthrin, measuring 13.5 days, 12 days, and 121.5 days, respectively. According to these findings, bifenthrin has a moderate amount of binding and stability in soil, which makes partial decomposition of parent and daughter molecules challenging. This research advances our knowledge of bifenthrin's deteriorating processes and aids in the creation of cutting-edge strategies for ecological restoration using natural processes.

摘要

为了全面理解每种农药与土壤及环境的行为和相互作用,对每种农药进行全面而细致的分析被认为是必要的。在本研究中,随机选取了10个具有不同特性的非均质土壤样本,进行了吸附试验以及使用生物降解、水解和光解的分解试验。对于吸附试验,采用了批次平衡法,该方法揭示了其对土壤理化特性的依赖性。联苯菊酯的分配系数(K )在7.27至25.89μg·ml之间变化, 值在0.92至0.99之间变化。每种土壤理化特性都与各种吸附结果相关,基于负热力学值表明存在放热吸附反应。联苯菊酯的水解、土壤诱导生物降解和光解过程的半衰期最短,分别为13.5天、12天和121.5天。根据这些发现,联苯菊酯在土壤中的结合和稳定性适中,这使得母体和子体分子的部分分解具有挑战性。这项研究推进了我们对联苯菊酯降解过程的认识,并有助于制定利用自然过程进行生态修复的前沿策略。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80bb/11614517/198b2fdce018/JAMC2024-8868954.001.jpg

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