Porter Zach, Shen Lingjia, Plumley Rajan, Burdet Nicolas G, Petsch Alexander N, Wen Jiajia, Drucker Nathan C, Peng Cheng, Chen Xiaoqian M, Fluerasu Andrei, Blackburn Elizabeth, Coslovich Giacomo, Hawthorn David G, Turner Joshua J
Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA 94025.
Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory and Stanford University, Menlo Park, CA 94025.
Proc Natl Acad Sci U S A. 2024 Dec 10;121(50):e2412182121. doi: 10.1073/pnas.2412182121. Epub 2024 Dec 4.
In unconventional superconductors, coupled charge and lattice degrees of freedom can manifest in ordered phases of matter that are intertwined. In the cuprate family, fluctuating short-range charge correlations can coalesce into a longer-range charge density wave (CDW) order which is thought to intertwine with superconductivity, yet the nature of the interaction is still poorly understood. Here, by measuring subtle lattice fluctuations in underdoped YBaCuO on quasi-static timescales (thousands of seconds) through X-ray photon correlation spectroscopy, we report sensitivity to both superconductivity and CDW. The atomic lattice shows remarkably faster relaxational dynamics upon approaching the superconducting transition at ≈ 65 K. By tracking the momentum dependence, we show that the intermediate scattering function almost monotonically scales with the relaxation distance of atoms away from their average positions above and in the presence of the CDW state, while this peculiar trend is reversed for other temperatures. These observations are consistent with an incipient CDW stabilized by local strain. This work provides insights into the crucial role of relaxational atomic fluctuations for understanding the electronic physics cuprates, which are inherently disordered due to carrier doping.
在非常规超导体中,耦合的电荷和晶格自由度可在相互交织的有序物质相中表现出来。在铜酸盐家族中,波动的短程电荷关联可合并为一种长程电荷密度波(CDW)序,人们认为这种序与超导性相互交织,但其相互作用的本质仍知之甚少。在此,我们通过X射线光子关联光谱法在准静态时间尺度(数千秒)上测量欠掺杂YBaCuO中的细微晶格波动,报告了对超导性和CDW的敏感性。当接近约65K的超导转变温度时,原子晶格显示出明显更快的弛豫动力学。通过追踪动量依赖性,我们表明,在CDW态之上且存在CDW态时,中间散射函数几乎随原子偏离其平均位置的弛豫距离单调变化,而在其他温度下这种特殊趋势则相反。这些观察结果与由局部应变稳定的初始CDW一致。这项工作为弛豫原子波动在理解铜酸盐电子物理学中的关键作用提供了见解,铜酸盐由于载流子掺杂而固有地无序。