Lee Dukhyung, Lee Youjin, Kim Dai-Sik
Ulsan National Institute of Science and Technology, Ulsan 44919, Republic of Korea.
Seoul National University, Seoul 08826, Republic of Korea.
Nanophotonics. 2023 Nov 6;13(7):1091-1097. doi: 10.1515/nanoph-2023-0557. eCollection 2024 Mar.
Bethe's theory predicts that scattering by a small hole on a thin perfect electric conductor (PEC) is presented as radiation by an in-plane magnetic dipole of the incident magnetic field direction. Even in the near-infrared range where metals are no more PEC, the magnetic dipole radiation of Bethe holes has been demonstrated. However, such Bethe holes' nature has not been addressed yet in the ultraviolet (UV) range where conductivity of metals becomes severely deteriorated. Meanwhile, UV plasmonics has been elevating its importance in spectroscopy and photochemistry, recognizing silicon (Si) as an alternative plasmonic metal featuring the interband transition in the UV range. In this work, we expanded the Bethe's theory's prediction to the UV range by investigating Si Bethe holes theoretically and experimentally in terms of the scattering pattern and polarization. Simulation results showed that the scattered field distribution resembles that of an in-plane magnetic dipole, and the dipole direction at oblique incidence is roughly given as the incident magnetic field direction with a deviation angle which can be predicted from the Fresnel equations. Simulation with various diameters showed that the magnetic dipole nature maintains with a diameter less than the quarter-wavelength and multipoles becomes noticeable for diameters larger than the half-wavelength. We performed scattering polarization measurement at 69-degree incidence, which confirms the theoretical analysis. The features of Si Bethe holes demonstrated here will be useful for designing UV plasmonic metasurfaces.
贝塞理论预测,薄的理想电导体(PEC)上的小孔散射表现为沿入射磁场方向的面内磁偶极子的辐射。即使在金属不再是PEC的近红外范围内,贝塞孔的磁偶极子辐射也已得到证实。然而,在金属电导率严重恶化的紫外(UV)范围内,这种贝塞孔的性质尚未得到研究。与此同时,紫外等离激元学在光谱学和光化学中的重要性不断提高,硅(Si)被认为是一种替代等离激元金属,在紫外范围内具有带间跃迁。在这项工作中,我们通过理论和实验研究了硅贝塞孔的散射图案和偏振,将贝塞理论的预测扩展到了紫外范围。模拟结果表明,散射场分布类似于面内磁偶极子的分布,斜入射时偶极子方向大致为入射磁场方向,偏差角可由菲涅耳方程预测。对不同直径的模拟表明,直径小于四分之一波长时磁偶极子性质保持不变,直径大于半波长时多极子变得明显。我们在69度入射角下进行了散射偏振测量,证实了理论分析。这里展示的硅贝塞孔的特性将有助于设计紫外等离激元超表面。