Enhanced radiative cooling with optical properties for low-temperature space cooling.

Passive daytime radiative cooling that could provide sub-ambient cooling emerges as a promising technology to reduce household energy consumption. Nonetheless, prevailing studies are predominantly focused on surface cooling, often overlooking its adaptability to enclosed spaces with active cooling technologies. Here we present a multilayer radiative cooling film (-MRC) with optical properties in the mid-infrared region, consisting of the nanoporous polyethylene films, the polyethylene oxide film, and silver nanowires. The top side of the -MRC functions as a conventional radiative cooling material to supply sub-ambient surface cooling, while the bottom side with low mid-infrared emissivity transfers limited heat via thermal radiation to the low-temperature enclosures. Our experiments validate that the -MRC possesses an enhanced space cooling performance in comparison to the conventional radiative cooling film. This work provides a valuable design concept for radiative cooling materials, thereby expanding their practical scenarios and contributing to reduce the carbon emission.