Gel-forming polysaccharides of traditional gel-like foods: Sources, structure, gelling mechanism, and advanced applications.

Gels are intermediates between solid and liquid with elastic and flowable characteristics whose three-dimensional networks can restrict water, air, and oil. They have extensive applications in modern times in biomedical engineering, electronics, environmental engineering, etc. However, gels have also been made as foods from ancient times for over a thousand years, such as pudding, tofu, and cheese. Among them, protein-based gel-like foods have continuously garnered significant attention and research. In contrast, some polysaccharide-based gel-like foods in southeast Asia, such as "liangfen", "green tofu", "ice jelly", "tamarind jelly", "konjac tofu", and "black grass jelly", have not been noticed until recent years regarding their compositions and gelling mechanisms. This review commences on six traditional gel-like foods mentioned above, which refer to six different types of plants and four kinds of gel-forming polysaccharides, including pectin, tamarind seed xyloglucan, konjac glucomannan, and Mesona chinensis polysaccharide. Recent progress and developments of these gel-forming polysaccharides on different gelling mechanisms are summarized. Due to differences in corresponding gel properties, these polysaccharides are applied in various fields, such as delivery systems, tissue engineering, wound dressings, and adsorbent materials. Future trends of these gels would potentially focus on manipulating the mechanical properties by modifying the flexibility of polysaccharide molecules and designing composite gels, as well as producing stimuli-responsive hydrogels and other desirable aspects to catch up with the properties of synthetic counterparts.