Thirugnanam Bavani, Mani Preeyanghaa, Almutairi Bader O, Sathishkumar Kuppusamy, Settu Munusamy
Department of Chemistry, Karpagam Academy of Higher Education, Coimbatore, 641021, India.
Center for Energy and Environment, Karpagam Academy of Higher Education, Coimbatore, 641021, India.
Environ Sci Pollut Res Int. 2024 Dec;31(59):66866-66877. doi: 10.1007/s11356-024-35728-y. Epub 2024 Dec 9.
To address the bottleneck issue of poor carrier separation and transfer efficiency in NiCoO photocatalyst, a novel 1D/2D-rod-on-rose-like NiCOO/BiOI nanohybrid with abundant OV's was successfully synthesized using a single-step hydrothermal method and employed to the photocatalytic degradation of Rhodamine B (RhB). The study revealed that the optimized NiCoO-OV/BiOI hybrid could possess superior photocatalytic degradation efficiency towards RhB degradation under visible light with a rate constant that was 3.8 and 3.03 times greater than that of BiOI and NiCoO-OV. Experimental findings indicated that the formation of NiCoCO-OV/BiOI heterojunction significantly improved the charge separation efficiency and facilitated the formation of surface OV's. These OVs enhanced photogenerated e-h separation and increased catalytic efficiency. Quenching experiments results confirmed that both holes and superoxide radicals are playing crucial roles in the degradation process. Thus, an oxygen vacancy and engineering NiCoCO-OV/BiOI heterojunction-enhanced degradation mechanism was proposed, offering insights for the integration of advanced oxidation technologies and the development of catalytic materials to enhance pollutant degradation efficiency.
