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Inorg Chem. 2020 Apr 6;59(7):4517-4526. doi: 10.1021/acs.inorgchem.9b03630. Epub 2020 Mar 18.
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validation ALERTS: what they mean and how to respond.验证警报：其含义及应对方法
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Dibromidooxido[(Z)-N'-(propan-2-yl-idene)benzohydrazidato](triphenyl-phosphane)rhenium(V).
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Graph-set analysis of hydrogen-bond patterns in organic crystals.有机晶体中氢键模式的图形集分析。
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三苯基鏻三氯（三苯基膦-κ）钴酸（II）苯二溶剂合物

Tri-phenyl-phospho-nium tri-chlorido-(tri-phenyl-phosphane-κ)cobaltate(II) benzene disolvate.

作者信息

Ndima Lubabalo, Hosten Eric Cyriel, Betz Richard

机构信息

Nelson Mandela University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth, 6031, South Africa.

出版信息

IUCrdata. 2024 Nov 22;9(Pt 11):x241121. doi: 10.1107/S2414314624011210. eCollection 2024 Nov.

DOI:10.1107/S2414314624011210
PMID:39649091
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11618865/
Abstract

The solvated title compound, (CHP)[CoCl(CHP)]·2CH, is the tri-phenyl-phospho-nium salt of an anionic Co chlorido coordination compound; the asymmetric unit features an ion-pair and two benzene solvent molecules. One of the solvent mol-ecules shows rotational disorder. C-H⋯Cl and P-H⋯Cl contacts connect the individual constituents into infinite chains extending parallel to [010].

摘要

溶剂化的标题化合物(CHP)[CoCl(CHP)]·2CH是一种阴离子氯化钴配位化合物的三苯基鏻盐；不对称单元包含一个离子对和两个苯溶剂分子。其中一个溶剂分子表现出旋转无序。C-H⋯Cl和P-H⋯Cl接触将各个组分连接成平行于[010]延伸的无限链。