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用于从电子废物中高效提取金和贵金属元素的咔唑-磷腈基聚合物。

Carbazole-Phosphazene Based Polymer for Efficient Extraction of Gold and Precious Elements from Electronic Waste.

作者信息

Cucu Evren, Ari Engin Betul, Tunc Murat, Altundas Ramazan, Sadak Ali Enis

机构信息

TUBITAK UME, Chemistry Group Laboratories, 41470, Gebze, Kocaeli, Türkiye.

Department of Chemistry, Gebze Technical University,, 41400, Gebze, Kocaeli, Türkiye.

出版信息

ACS Omega. 2024 Nov 18;9(48):47884-47892. doi: 10.1021/acsomega.4c09068. eCollection 2024 Dec 3.

Abstract

The continuous advancement of industry and technology has significantly increased electronic waste, which contributes to the depletion of valuable metal reserves. Therefore, it is crucial to recycle precious metals in electronic waste effectively and sustainably. This study introduces a novel approach by applying a carbazole-phosphazene-based polymer, EBE-06, in a two-stage leaching method for efficient metal extraction. In the first leaching stage, tin is selectively separated using an acid solution at a controlled pH. In the second stage, valuable metals such as gold are recovered through adsorption onto EBE-06. The polymer exhibited a 99% gold adsorption rate within 1 h, independent of pH, and a maximum adsorption capacity of 1.787 g of gold per gram of polymer. The desorption process yielded 95% efficiency, with the polymer maintaining 94% efficiency over three cycles of use.

摘要

工业和技术的不断进步显著增加了电子垃圾,这导致了宝贵金属储备的枯竭。因此,有效且可持续地回收电子垃圾中的贵金属至关重要。本研究引入了一种新方法,通过应用基于咔唑-磷腈的聚合物EBE-06,采用两阶段浸出法进行高效金属提取。在第一浸出阶段,使用控制pH值的酸性溶液选择性分离锡。在第二阶段,通过吸附到EBE-06上回收金等贵金属。该聚合物在1小时内金吸附率达到99%,与pH值无关,每克聚合物的最大吸附容量为1.787克金。解吸过程效率达到95%,该聚合物在三个使用周期内保持94%的效率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e57/11618425/dd1539290f97/ao4c09068_0001.jpg

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