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无机非金属玻璃中的熵工程

Entropy engineering in inorganic non-metallic glass.

作者信息

Feng Xu, Yue Yuanzheng, Qiu Jianrong, Jain Himanshu, Zhou Shifeng

机构信息

State Key Laboratory of Luminescent Materials and Devices, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China.

Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and Devices, Guangzhou 510640, China.

出版信息

Fundam Res. 2022 Feb 17;2(5):783-793. doi: 10.1016/j.fmre.2022.01.030. eCollection 2022 Sep.

DOI:10.1016/j.fmre.2022.01.030
PMID:39659953
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11630721/
Abstract

Advances in developing high entropy alloys and ceramics with improved physical properties have greatly broadened their application field from aerospace industry, public transportation to nuclear plants. In this review, we describe the concept of entropy engineering as applicable to inorganic non-metallic glasses, especially for tailoring and enhancing their mechanical, electrical, and optical properties. We also present opportunities and challenges in calculating entropy of inorganic non-metallic glass systems, correlating entropy to glass formation, and in developing functional inorganic non-metallic glasses via the entropy concept.

摘要

开发具有改进物理性能的高熵合金和陶瓷方面的进展极大地拓宽了它们的应用领域,从航空航天工业、公共交通到核电站。在这篇综述中,我们描述了适用于无机非金属玻璃的熵工程概念,特别是用于定制和增强它们的机械、电学和光学性能。我们还介绍了在计算无机非金属玻璃系统的熵、将熵与玻璃形成相关联以及通过熵概念开发功能性无机非金属玻璃方面的机遇和挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/f976c36845ee/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/5461a8e88ccc/ga1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/f9e60642dfd2/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/f70d0ffbf5e5/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/f28b3e25f6c8/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/c04b8c70b3a7/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/8a1d3e9774bc/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/f976c36845ee/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/5461a8e88ccc/ga1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/f9e60642dfd2/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/f70d0ffbf5e5/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/f28b3e25f6c8/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/c04b8c70b3a7/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/8a1d3e9774bc/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd99/11630721/f976c36845ee/gr6.jpg

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引用本文的文献

1
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本文引用的文献

1
Tuning element distribution, structure and properties by composition in high-entropy alloys.通过高熵合金的成分来调整元素分布、结构和性能。
Nature. 2019 Oct;574(7777):223-227. doi: 10.1038/s41586-019-1617-1. Epub 2019 Oct 9.
2
Pressureless Crystallization of Glass for Transparent Nanoceramics.用于透明纳米陶瓷的玻璃无压结晶
Adv Sci (Weinh). 2019 Jun 28;6(17):1901096. doi: 10.1002/advs.201901096. eCollection 2019 Sep 4.
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Topological Origins of the Mixed Alkali Effect in Glass.玻璃中混合碱效应的拓扑起源
J Phys Chem B. 2019 Aug 29;123(34):7482-7489. doi: 10.1021/acs.jpcb.9b06512. Epub 2019 Aug 15.
4
Understanding Glass through Differential Scanning Calorimetry.通过差示扫描量热法了解玻璃。
Chem Rev. 2019 Jul 10;119(13):7848-7939. doi: 10.1021/acs.chemrev.8b00510. Epub 2019 May 23.
5
High-entropy high-hardness metal carbides discovered by entropy descriptors.熵描述符发现的高熵高硬度金属碳化物。
Nat Commun. 2018 Nov 26;9(1):4980. doi: 10.1038/s41467-018-07160-7.
6
Processing and Properties of High-Entropy Ultra-High Temperature Carbides.高熵超高温碳化物的加工与性能
Sci Rep. 2018 Jun 5;8(1):8609. doi: 10.1038/s41598-018-26827-1.
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Thermometer Effect: Origin of the Mixed Alkali Effect in Glass Relaxation.温度计效应:玻璃弛豫中混合碱效应的起源。
Phys Rev Lett. 2017 Sep 1;119(9):095501. doi: 10.1103/PhysRevLett.119.095501. Epub 2017 Aug 31.
8
Ionic conductivity and mixed-ion effect in mixed alkali metaphosphate glasses.偏磷酸混合碱金属玻璃中的离子电导率和混合离子效应
Phys Chem Chem Phys. 2017 Mar 1;19(9):6594-6600. doi: 10.1039/c6cp07876a.
9
High-Entropy Metal Diborides: A New Class of High-Entropy Materials and a New Type of Ultrahigh Temperature Ceramics.高熵金属二硼化物:一类新型高熵材料和一种新型超高温陶瓷。
Sci Rep. 2016 Nov 29;6:37946. doi: 10.1038/srep37946.
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Entropy-stabilized oxides.熵稳定氧化物
Nat Commun. 2015 Sep 29;6:8485. doi: 10.1038/ncomms9485.