Yu Fengwei, Liu Qi, Ding Yan, Zhang Wei, Ma Ming-Guo
MOE Engineering Research Center of Forestry Biomass Materials and Bioenergy, Research Center of Biomass Clean Utilization, Beijing Key Laboratory of Lignocellulosic Chemistry, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, PR China.
MOE Engineering Research Center of Forestry Biomass Materials and Bioenergy, Research Center of Biomass Clean Utilization, Beijing Key Laboratory of Lignocellulosic Chemistry, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, PR China; Department of Biomedical Engineering, Guangdong Provincial Key Laboratory of Advanced Biomaterials, Institute of Innovative Materials, Southern University of Science and Technology, Shenzhen 518055, PR China..
Int J Biol Macromol. 2025 Jan;287:138557. doi: 10.1016/j.ijbiomac.2024.138557. Epub 2024 Dec 9.
As science and technology progress swiftly, the demand for high-performance composite films designed to shield against electromagnetic interference (EMI) and for strain sensing applications has significantly increased, making these films essential components for the future generation of smart wearable electronics. However, designing and developing multifunctional flexible composite films remains a considerable challenge. This study employed vacuum-assisted filtration techniques combined with calcium ion cross-linking to create multifunctional MXene/sodium alginate/liquid metal (MSL) composite films exhibiting exceptional EMI shielding and strain sensing capabilities. The mechanical strength of the MSL composite films was optimized by implementing continuous hydrogen bonding and ionic interactions among MXene, sodium alginate, liquid metal (LM), and calcium ions, resulting in a tensile strength of 71.71 MPa. The composite film exhibits excellent electromagnetic absorption properties, resulting in an exceptional EMI shielding efficacy of 50.61 dB and a specific shielding effectiveness value of 7563 dB·cm·g. This is due to the heterogeneous interface between MXene and LM nanoparticles. Furthermore, the composite film exhibits favorable electrothermal and photothermal conversion capabilities. The film can be a flexible sensor to detect human motion, contingent on the conductive network between MXene and LM. This research illustrates the potential of multifunctional MSL composite films for EMI shielding and human motion monitoring, offering a promising pathway for creating adaptable wearable electronics in challenging electromagnetic conditions.
随着科学技术的迅速发展,对用于电磁干扰(EMI)屏蔽和应变传感应用的高性能复合薄膜的需求显著增加,使这些薄膜成为下一代智能可穿戴电子产品的关键组件。然而,设计和开发多功能柔性复合薄膜仍然是一项重大挑战。本研究采用真空辅助过滤技术结合钙离子交联,制备出具有优异电磁干扰屏蔽和应变传感能力的多功能MXene/海藻酸钠/液态金属(MSL)复合薄膜。通过在MXene、海藻酸钠、液态金属(LM)和钙离子之间实现连续的氢键和离子相互作用,优化了MSL复合薄膜的机械强度,其拉伸强度达到71.71MPa。该复合薄膜具有优异的电磁吸收性能,电磁干扰屏蔽效能高达50.61dB,比屏蔽效能值为7563dB·cm·g。这归因于MXene与LM纳米颗粒之间的异质界面。此外,该复合薄膜还具有良好的电热和光热转换能力。基于MXene与LM之间的导电网络,该薄膜可作为一种柔性传感器来检测人体运动。本研究阐明了多功能MSL复合薄膜在电磁干扰屏蔽和人体运动监测方面的潜力,为在具有挑战性的电磁条件下制造适应性强的可穿戴电子产品提供了一条有前景的途径。