Improved Catalyst Performance for the Oxygen Evolution Reaction under a Chiral Bias.

The oxygen evolution reaction (OER) remains an important bottleneck for widespread implementation of a hydrogen economy. While improvements in the OER can be realized by spin polarizing the reaction intermediates, these methods often rely on applying external magnetic fields to ferromagnetic catalysts or by adsorbing chiral molecules onto the catalyst. Here, we show that the addition of chiral additives to the conductive binder supporting the catalysts enhances the selectivity for O formation and results in exceedingly high mass activities. The results are explained within the context of a statistical model in which the additives are hypothesized to act as a localized chiral bias that enhances radical intermediate coupling. More broadly, these studies illustrate a flexible design motif for improving OER catalysis that persists under different pH conditions, is independent of the choice of catalyst, and can be extrapolated to other chemical reactions.