Li Zhaolong, Peng Kaiming, Ji Nannan, Zhang Wenlong, Tian Wenrou, Gao Zhenfei
State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University Yinchuan 750021 China.
School of Materials Science and Engineering, Beijing Science and Engineering Center for Nanocarbons, Peking University Beijing 100871 China.
Nanoscale Adv. 2024 Dec 10;7(2):419-432. doi: 10.1039/d4na00701h. eCollection 2025 Jan 14.
The interaction of microwave radiation with carbon-based materials induces rapid, instantaneous heating. When combined with the plasma excitation capabilities of microwaves, this property presents novel avenues for synthesizing carbon-based materials that require high temperatures and catalytic activity. This review investigates the response of carbon-based materials to microwave radiation, analyzes the dielectric loss mechanism responsible for heat generation, and details the microwave plasma excitation mechanisms employed in the synthesis and processing of carbon-based materials. Furthermore, the structure of microwave reactors is discussed, followed by a discussion of their diverse applications in both laboratory and industrial settings. Lastly, the review addresses the challenges associated with the practical implementation of microwave technology and explores future development prospects, with a particular focus on the application of microwaves in carbon-based material synthesis.
微波辐射与碳基材料的相互作用会引发快速、即时的加热。当与微波的等离子体激发能力相结合时,这一特性为合成需要高温和催化活性的碳基材料提供了新途径。本综述研究了碳基材料对微波辐射的响应,分析了导致发热的介电损耗机制,并详细阐述了在碳基材料合成与加工中采用的微波等离子体激发机制。此外,还讨论了微波反应器的结构,随后探讨了它们在实验室和工业环境中的各种应用。最后,本综述阐述了与微波技术实际应用相关的挑战,并探索了未来的发展前景,特别关注微波在碳基材料合成中的应用。