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低成本旋涂:一种用于经济高效薄膜沉积的3D打印全机械替代方案。

Spin coating on a budget: A 3D-Printed all-mechanical alternative for cost-effective thin-film deposition.

作者信息

Kalafatis Apostolos, Theofylaktos Lazaros, Stergiopoulos Thomas

机构信息

Institute of Nanoscience and Nanotechnology, National Center for Scientific Research "Demokritos", Aghia Paraskevi, Athens 15341, Greece.

Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece.

出版信息

HardwareX. 2024 Jun 25;19:e00547. doi: 10.1016/j.ohx.2024.e00547. eCollection 2024 Sep.

Abstract

Spin coating stands out as the most employed thin-film deposition technique across a variety of scientific fields. Particularly in the past two decades, spin coaters have become increasingly popular due to the emergence of solution-processed semiconductors such as quantum dots and perovskites. However, acquiring commercial spin coaters from reputable suppliers remains a significant financial burden for many laboratories, particularly for smaller research or educational facilities. Prompted by the simple mechanical principles of the device, in this work, we present a 3D-printed analogue that can be printed and assembled in under 10 h and costs less than 5 euros per device. The operating principle is fully mechanical since the rotating motion is induced by gas flow. It does not require any additional components such as DC motors, motor drivers, circuitry or software and thus it can be fully operational off the grid. Additionally, the gas flow generates a purging effect that was found to be rather advantageous for film formation. To prove the effectiveness of this device, we have employed it to fabricate planar thin-film antimony sulfide (Sb S ) solar cells. The optoelectronic characteristics of solar cells revealed noteworthy improvements, particularly in terms of repeatability, when compared to those fabricated with a commercial spin coater.

摘要

旋涂是各种科学领域中应用最广泛的薄膜沉积技术。特别是在过去二十年中,由于量子点和钙钛矿等溶液处理半导体的出现,旋涂机越来越受欢迎。然而,从知名供应商处购买商用旋涂机对许多实验室来说仍然是一项巨大的财务负担,尤其是对于较小的研究或教育机构而言。受该设备简单机械原理的启发,在这项工作中,我们展示了一种3D打印的类似物,它可以在不到10小时内打印并组装完成,每个设备成本不到5欧元。其工作原理完全是机械的,因为旋转运动是由气流引起的。它不需要任何额外的组件,如直流电机、电机驱动器、电路或软件,因此可以完全脱离电网运行。此外,气流产生的吹扫效应被发现对成膜相当有利。为了证明该设备的有效性,我们用它来制造平面薄膜硫化锑(Sb₂S₃)太阳能电池。与用商用旋涂机制备的太阳能电池相比,其光电特性有了显著改善,尤其是在重复性方面。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b595/11637174/7febd40fc1f7/ga1.jpg

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