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用于锂金属固态电池的纳米受限LiBH快速锂离子传导相的稳定化

Stabilization of fast lithium-ionic conduction phase of nanaoconfined LiBH for lithium metal solid-state batteries.

作者信息

Zeng Shunqin, Ren Kaixiang, Ding Hongfei, Xu Shendong, Li Hai-Wen, Li Yongtao

机构信息

School of Materials Science and Engineering & Low-Carbon New Materials Research Center, Anhui University of Technology, Maanshan 243002, China.

College of Chemistry and Materials Engineering, Huaihua University, Huaihua, 418000, China.

出版信息

Chem Commun (Camb). 2025 Jan 9;61(5):929-932. doi: 10.1039/d4cc05329j.

Abstract

The nanoconfinement of LiBH into mesoporous AlO as a fast lithium-ion conductor is presented, and its high-temperature phase is retained at near-room temperature. It exhibits an excellent electrochemical stability and Li conductivity of 3.2 × 10 S cm at 75 °C, which represents an increase of nearly three orders of magnitude compared to the pristine one.

摘要

本文介绍了将LiBH纳米限域于介孔AlO中作为快速锂离子导体的情况,其高温相在接近室温的条件下得以保留。它表现出优异的电化学稳定性,在75℃时的锂电导率为3.2×10 S cm,与原始材料相比提高了近三个数量级。

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