Zhang Qi, Zhou Zhijun, Yi Xi, Wang Shuyang, Xing Aoxue, Wang Chenzhu
Key Laboratory of Enhanced Oil Recovery, Northeast Petroleum University, Daqing, Heilongjiang 163000, China.
Civil Engineering and Architecture, Northeast Petroleum University, Daqing, Heilongjiang 163000, China.
ACS Omega. 2024 Nov 26;9(49):48438-48451. doi: 10.1021/acsomega.4c06741. eCollection 2024 Dec 10.
After many years of mining in the Fang2 block of the Songfangtun oilfield, the conventional water drive development method can no longer meet the requirement of greatly improving the recovery rate, and ternary composite drive (TCD) technology is adopted for this purpose. TCD is one of the most important methods to further improve crude oil recovery, and it has entered the industrialization and promotion stage, but there are still problems of fouling in the injection and extraction system and high production and maintenance costs. In order to reduce formation damage and improve recovery in the Songfangtun oilfield, an alkali-free microemulsion system was developed by replacing the weak base sodium carbonate with sodium chloride, but its emulsification capacity was weak and the recovery enhancement value was lower than that of the weak base TCD. In order to improve the emulsification performance of the alkali-free microemulsion and enhance the effect of oil repulsion, an alkali-free microemulsion oil-repellent system was developed on the basis of the alkali-free ternary system by using the compounding of surfactant, alcohol, and sodium chloride. Through indoor physical modeling experiments, it was concluded that the SDBS alkali-free microemulsion system had the best effect on improving crude oil rheology and viscosity reduction, and the lowest interfacial tension of 9.4 × 10 mN/m in the solution system when the mass fraction was 4%, with the maximum recovery rate of 47.03%, and the decrease in water content of 9.3%. Through molecular dynamics simulation and microemulsion oil-repellent coefficient, it is concluded that the alkali-free SDBS microemulsion system can greatly reduce the interaction force between crude oil and rock, with the lowest peak value of radial distribution function of 4.21, and the oil-repellent coefficient of of 5.85; CMG reservoir numerical simulation software is adopted to verify the chemical repellent numerical simulation of Fang2 block, which shows that the recovery degree of SDBS alkali-free microemulsion system is 24.8% higher than that of water repellent, with the cumulative increase of 213.6 thousand tons of oil. The developed alkali-free microemulsion system not only realizes the goal of ternary composite alkalinity-free but also achieves the purpose of greatly improving the recovery rate and reducing the cost and increasing efficiency. It has a broad application prospect and can also provide a technical reference for the efficient development of other old oilfields with land-phase sandstone.
在宋芳屯油田芳2区块历经多年开采后,传统水驱开发方式已无法满足大幅提高采收率的需求,为此采用了三元复合驱(TCD)技术。三元复合驱是进一步提高原油采收率的重要方法之一,已进入工业化推广阶段,但仍存在注采系统结垢以及生产维护成本高等问题。为减少宋芳屯油田地层伤害并提高采收率,通过用氯化钠替代弱碱碳酸钠开发了无碱微乳液体系,但其乳化能力较弱,采收率增加值低于弱碱三元复合驱。为提高无碱微乳液的乳化性能并增强驱油效果,在无碱三元体系基础上,通过表面活性剂、醇和氯化钠复配开发了无碱微乳液驱油体系。通过室内物理模拟实验得出,SDBS无碱微乳液体系在改善原油流变性和降黏方面效果最佳,在溶液体系中质量分数为4%时界面张力最低,为9.4×10 mN/m,最大采收率为47.03%,含水率下降9.3%。通过分子动力学模拟和微乳液驱油系数得出,无碱SDBS微乳液体系可大幅降低原油与岩石间的相互作用力,径向分布函数最低峰值为4.21,驱油系数为5.85;采用CMG油藏数值模拟软件对芳2区块进行化学驱数值模拟验证,结果表明SDBS无碱微乳液体系采收程度比水驱提高24.8%,累计增油21.36万吨。所开发的无碱微乳液体系不仅实现了三元复合无碱化目标,还达到了大幅提高采收率、降低成本和提高效益的目的。具有广阔的应用前景,也可为其他陆相砂岩老油田的高效开发提供技术参考。