Electrochemical ocean iron fertilization and alkalinity enhancement approach toward CO sequestration.

Achieving net-zero emissions by 2050 requires the development of effective negative emission techniques, including ocean-based approaches for CO sequestration. However, the implementation and testing of marine CO removal (mCDR) techniques such as ocean iron fertilization (OIF) or ocean alkalinity enhancement (OAE) face significant challenges. Herein, a novel self-operating electrochemical technology is presented that not only combines OIF and OAE, but also recovers hydrogen gas (H) from seawater, hence offering a promising solution for achieving quantifiable and transparent large-scale mCDR. Experimental results show that the electrochemical OIF (EOIF) can not only increase the concentration of ferrous iron (Fe) by 0-0.5 mg/L, but also significantly increases the seawater pH by 8% (., a 25% decrease in the hydrogen ions concentration). The release of iron (Fe/Fe) can be regulated by adjusting the magnitude of the electric current and its form (e.g., pulsed current and polarity reversal), as well as by optimizing the electrode material and geometry. In certain ocean regions, enhanced iron concentrations stimulate the naturally occurring biological carbon pump (BCP), leading to increased phytoplankton growth, CO uptake, and subsequent export of carbon to the deep ocean. Simultaneously, the system increases seawater alkalinity and the buffer capacity, enhancing CO solubility and storage in the shallow ocean through the solubility pump. The obtained measurements demonstrate the scalability of EOIF and its ability to operate using solar energy at a lower cost. Overall, the proposed EOIF technology offers a practical, effective, and sustainable solution for addressing climate change on a large scale.