Aroeira Gustavo J R, Kairys Kyle T, Ribeiro Raphael F
Department of Chemistry and Cherry Emerson Center for Scientific Computation, Emory University, Atlanta, GA, USA.
Nanophotonics. 2024 Feb 21;13(14):2553-2564. doi: 10.1515/nanoph-2023-0797. eCollection 2024 Jun.
Excitation energy transport can be significantly enhanced by strong light-matter interactions. In the present work, we explore intriguing features of coherent transient exciton wave packet dynamics on a lossless disordered polaritonic wire. Our main results can be understood in terms of the effective exciton group velocity, a new quantity we obtain from the polariton dispersion. Under weak and moderate disorder, we find that the early wave packet spread velocity is controlled by the overlap of the initial exciton momentum distribution and its effective group velocity. Conversely, when disorder is stronger, the initial state is nearly irrelevant, and red-shifted cavities support excitons with greater mobility. Our findings provide guiding principles for optimizing ultrafast coherent exciton transport based on the magnitude of disorder and the polariton dispersion. The presented perspectives may be valuable for understanding and designing new polaritonic platforms for enhanced exciton energy transport.
强光与物质相互作用可显著增强激发能传输。在本工作中,我们探索了无损无序极化子线中相干瞬态激子波包动力学的有趣特征。我们的主要结果可以通过有效激子群速度来理解,这是我们从极化子色散中获得的一个新量。在弱无序和中等无序情况下,我们发现早期波包的传播速度由初始激子动量分布与其有效群速度的重叠控制。相反,当无序更强时,初始状态几乎无关紧要,并且红移腔支持具有更大迁移率的激子。我们的发现为基于无序程度和极化子色散优化超快相干激子传输提供了指导原则。所呈现的观点对于理解和设计用于增强激子能量传输的新型极化子平台可能具有重要价值。