Ying Wenxiang, Chng Benjamin X K, Delor Milan, Huo Pengfei
Department of Chemistry, University of Rochester, Rochester, NY, USA.
Department of Physics and Astronomy, University of Rochester, Rochester, NY, USA.
Nat Commun. 2025 Jul 29;16(1):6950. doi: 10.1038/s41467-025-62276-x.
Cavity exciton-polaritons exhibit ballistic transport and can achieve 100 μm in one picosecond. This ballistic transport significantly enhances mobility compared to that of bare excitons, which often move diffusively and become the bottleneck for energy conversion and transfer devices. Despite being robustly reproduced in experiments and simulations, there is no microscopic theory available for describing the group velocity v of polariton transport and its renormalization. In this work, we derive an analytic expression for v renormalization. The theory suggests the v renormalization is caused by phonon-mediated transitions between the lower polariton (LP) states and the dark states. The theory predicts that the renormalization magnitude depends on both exciton-phonon coupling strength and temperature, which are in quantitative agreement with numerical quantum dynamics simulations. Our results provide theoretical insights and a predictive analytical theory for understanding cavity-enhanced exciton-polariton transport.
腔激子极化激元表现出弹道输运,在一皮秒内可实现100微米的传输距离。与裸激子相比,这种弹道输运显著提高了迁移率,裸激子通常呈扩散运动,成为能量转换和转移器件的瓶颈。尽管在实验和模拟中都能可靠地重现,但目前还没有微观理论可用于描述极化激元输运的群速度v及其重整化。在这项工作中,我们推导了v重整化的解析表达式。该理论表明,v重整化是由低极化激元(LP)态与暗态之间的声子介导跃迁引起的。该理论预测,重整化幅度取决于激子 - 声子耦合强度和温度,这与数值量子动力学模拟在定量上是一致的。我们的结果为理解腔增强激子极化激元输运提供了理论见解和预测性分析理论。