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芴的多种用途干预:一个庞大的家族

An Intervention into the Diverse Utilities of Fluorenes: A Brobdingnagian Family.

作者信息

Sreekumar Anjana, Nair Ajil R, Raksha C, Swayamprabha Sujith Sudheendran, Sivan Akhil

机构信息

Department of Chemistry, Amrita Vishwa Vidyapeetham, Amritapuri, Kollam, Kerala, 690525, India.

Bruckewell Technology Co., Ltd., 13F., No. 251, Dong Sec. 1, Guangming 6 Rd., Zhubei City, Hsinchu County, 302044, Taiwan.

出版信息

Top Curr Chem (Cham). 2024 Dec 16;383(1):4. doi: 10.1007/s41061-024-00485-6.

DOI:10.1007/s41061-024-00485-6
PMID:39680345
Abstract

The keyword "Fluorene" search in SciFinder found more than 57,000 results, including high-impact journal articles, review articles, patents, books, proceedings, etc. Against this background, a detailed enquiry has been made by our group on various classes of fluorenes and their relevancy. For the past several decades, fluorene and its related compounds have experienced extensive studies, which are attributed to the vast range of applications they possess in various fields like sensors, polymers, OLED devices and even in the pharmaceutical industries. Since fluorene is an important member of the 'polyaromatic-hydrocarbon' family and has proved its relevancy in multidisciplinary areas, summarising those milestones might be worthwhile for future researchers. Here, we intend to highlight the key applications of fluorene derivatives in the form of a review article and have put much effort into consolidating some of their most imperative applications, including those in sensors and medicinal, optoelectronic and electrochemical fields. The manuscript divides the fluorene family into multiple subclasses, counting mono- and polyfluorenes, spirofluorenes, silicon-cored fluorenes, indenofluorenes, etc., based on their structure, and portrays all the critical properties of each class. Since fluorenes are globally accepted as outstanding candidates for numerous applications and practicalities, our effort may find crucial acceptance in the near future.

摘要

在SciFinder中搜索关键词“芴”得到了超过57000条结果,包括高影响力的期刊文章、综述文章、专利、书籍、会议论文集等。在此背景下,我们团队对各类芴及其相关性进行了详细的探究。在过去的几十年里,芴及其相关化合物经历了广泛的研究,这归因于它们在传感器、聚合物、有机发光二极管器件甚至制药行业等各个领域拥有广泛的应用。由于芴是“多环芳烃”家族的重要成员,并且已在多学科领域证明了其相关性,总结这些里程碑对未来的研究人员可能是有价值的。在此,我们打算以综述文章的形式突出芴衍生物的关键应用,并付出了很多努力来巩固它们的一些最重要的应用,包括在传感器、医药、光电和电化学领域的应用。该手稿根据芴家族的结构将其分为多个子类,包括单芴和聚芴、螺芴、硅核芴、茚并芴等,并描述了每一类的所有关键特性。由于芴在全球范围内被公认为众多应用和实用性的优秀候选物,我们的努力可能在不久的将来获得重要认可。

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本文引用的文献

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Syntheses and Properties of Hole-Transporting Biindenofluorenes.空穴传输双茚并芴的合成与性质
Org Lett. 2024 Apr 5;26(13):2617-2622. doi: 10.1021/acs.orglett.4c00630. Epub 2024 Mar 21.
2
In Situ Thermal Cross-Linking of 9,9'-Spirobifluorene-Based Hole-Transporting Layer for Perovskite Solar Cells.用于钙钛矿太阳能电池的基于9,9'-螺二芴的空穴传输层的原位热交联
ACS Appl Mater Interfaces. 2024 Jan 10;16(1):1206-1216. doi: 10.1021/acsami.3c13950. Epub 2023 Dec 20.
3
Dihydroindenofluorenes as building units in organic semiconductors for organic electronics.
二氢茚并芴作为用于有机电子学的有机半导体中的构建单元。
Chem Soc Rev. 2023 Oct 2;52(19):6754-6805. doi: 10.1039/d1cs00993a.
4
Thermally cross-linkable fluorene-based hole transporting materials: synthesis, characterization, and application in perovskite solar cells.可热交联的芴基空穴传输材料:合成、表征及在钙钛矿太阳能电池中的应用
RSC Adv. 2023 Sep 8;13(38):26933-26939. doi: 10.1039/d3ra03492e. eCollection 2023 Sep 4.
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Solution-Processable Indenofluorenes on Polymer Brush Interlayer: Remarkable N-Channel Field-Effect Transistor Characteristics under Ambient Conditions.聚合物刷中间层上可溶液加工的茚并芴:在环境条件下具有显著的N沟道场效应晶体管特性。
ACS Appl Mater Interfaces. 2023 Sep 6;15(35):41666-41679. doi: 10.1021/acsami.3c07365. Epub 2023 Aug 15.
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