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通过设计一种相容剂对废弃牛毛进行回收利用,以制备可持续的热塑性淀粉-未处理牛毛复合材料。

Recycling of Bovine Hair Waste Through the Design of a Compatibilizing Agent for Sustainable Thermoplastic Starch-Untreated Bovine Hair Composites.

作者信息

Mora-Maldonado Luz Elena, Estrada-Monje Anayansi, Zitzumbo-Guzmán Roberto, Rodríguez-Sánchez Isis, Baldenegro-Pérez Leonardo, Piñón-Balderrama Claudia Ivone, Rodríguez-Llamazares Saddys, Zaragoza-Contreras Erasto Armando

机构信息

Centro de Innovación Aplicada en Tecnologías Competitivas, León 37545, Mexico.

Departamento de Formación Básica Disciplinaria, Unidad Profesional Interdisciplinaria de Ingeniería Campus Guanajuato, Instituto Politécnico Nacional, UPIIG-IPN, Silao de la Victoria 36275, Mexico.

出版信息

Polymers (Basel). 2024 Dec 6;16(23):3432. doi: 10.3390/polym16233432.

Abstract

Bovine hair waste was chemically modified to obtain a coupling agent (CA) for the compatibilization of thermoplastic starch (TPS)-unmodified bovine hair waste (UH) composites. The composites processed with CA presented improved tensile strength (3.5 MPa) compared to TPS-UH composites without CA (1.25 MPa). An interaction mechanism to describe the improvement in mechanical properties and thermal stability was postulated based on Fourier-transform infrared spectroscopy (FTIR) and density functional theory (DFT). In addition, optical and electron microscopy showed that CA favored the adhesion of UH to TPS. Global results suggested the formation of a CA-UH network that interacts with the TPS matrix. Obtaining composites from waste from the tanning industry can contribute to the development of a more responsible and sustainable industry and represents an opportunity to reduce the environmental impact of one of the most important industries globally. It is worth mentioning that this research is aligned with the sustainable development goals (SDGs) proposed by the United Nations, which promotes sustainable industrialization and the promotion of innovation.

摘要

对牛毛废料进行化学改性,以获得一种偶联剂(CA),用于热塑性淀粉(TPS)与未改性牛毛废料(UH)复合材料的增容。与未使用CA的TPS-UH复合材料(1.25MPa)相比,使用CA加工的复合材料的拉伸强度有所提高(3.5MPa)。基于傅里叶变换红外光谱(FTIR)和密度泛函理论(DFT),提出了一种相互作用机制来描述力学性能和热稳定性的改善。此外,光学显微镜和电子显微镜显示,CA有利于UH与TPS的粘合。总体结果表明形成了与TPS基体相互作用的CA-UH网络。从制革行业的废料中获得复合材料有助于发展更具责任感和可持续性的产业,并且是减少全球最重要产业之一对环境影响的一个契机。值得一提的是,本研究符合联合国提出的可持续发展目标(SDGs),该目标促进可持续工业化和创新推广。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4e/11644711/681d8f5f8f2a/polymers-16-03432-g001.jpg

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