The Effect of TiO on the Dielectric Performance of ZrO and NbO Pre-Doped CaCuTiO Ceramics.

In this work, the effects of different sintering temperatures and TiO concentrations on the dielectric properties of ZrO and NbO pre-doped CaCuTiO (CCTO) ceramics were investigated. These doped ceramics were sintered at temperatures of 1020, 1030, and 1040 °C, exhibiting the lowest dielectric loss of 0.01, which consistently remained below 0.03 across a wide frequency range from 10 to 10 Hz. Simultaneously, they maintained a high dielectric constant of more than 3000 and remarkably met the requirements for an X8P capacitor (Δε' ≤ ±10% at temperature range from -55 to 150 °C). It was clarified that TiO doping increased grain boundary resistance, leading to the reduced dielectric loss, and elevated the grain boundary activation energy, thereby enhancing the temperature stability. The TiO-doped CCTO-based ceramics also demonstrated reduced sensitivity to variations in sintering temperature, highlighting their excellent manufacturability. This characteristic holds great promise for the fabrication of CCTO-based ceramics, which usually exhibit poor repetitiveness.