Kligys Modestas, Girskas Giedrius
Institute of Building Materials, Faculty of Civil Engineering, Vilnius Gediminas Technical University (VILNIUS TECH), 10223 Vilnius, Lithuania.
Materials (Basel). 2024 Dec 7;17(23):6000. doi: 10.3390/ma17236000.
The increased early hydration rate of high early strength cement has economic advantages in many civil engineering fields (faster formwork removal or earlier demoulding of precast elements). Styrene-butadiene rubber (SBR) latex is the most common polymer in aqueous dispersions suitable for admixing in cement-based materials. It allows the designing of structures with specific properties for a variety of applications. The analysis of literature sources has shown that different properties of SBR latex-modified cement-based material samples reported were usually measured at 3, 7, 14, and 28 days of hardening. In this research, the authors decided to investigate a combined effect of high early strength Portland cement, characterized by an increased hydration rate, and SBR latex able to retard this process for a prolonged hardening period-up to 90 days in modified mortar samples. This study covers the results of the effect of different amounts of SBR latex (5%, 10%, 15%, and 20%) on the properties of modified mortar samples with a constant water-to-cement ratio prepared with high early strength Portland cement 42.5 R. The mortar samples were prepared from local raw materials produced by the Lithuanian companies. The properties, such as dry bulk density, ultrasonic pulse velocity, capillary water absorption, compressive and flexural strengths, and toughness, after three different hardening periods (7, 28, and 90 days) of the mortar samples were investigated. The applied mathematical-statistical methods allowed a detailed prognosis of the dependence between the dry bulk density and the strength properties of modified mortar samples. The combination of 42.5 R strength class Portland cement with the SBR latex in amounts ranging from 5% to 20% seems to be suitable for designing durable structures with specific properties.
高早强水泥早期水化速率的提高在许多土木工程领域具有经济优势(更快拆除模板或更早预制构件脱模)。丁苯橡胶(SBR)乳胶是适用于水泥基材料掺合的水性分散体中最常见的聚合物。它能设计出具有特定性能的结构以用于各种应用。对文献资料的分析表明,所报道的SBR乳胶改性水泥基材料样品的不同性能通常在硬化3、7、14和28天时进行测量。在本研究中,作者决定研究水化速率提高的高早强波特兰水泥与能够在长达90天的延长硬化期内延缓这一过程的SBR乳胶在改性砂浆样品中的综合作用。本研究涵盖了不同用量(5%、10%、15%和20%)的SBR乳胶对用高早强波特兰水泥42.5R制备的水灰比恒定的改性砂浆样品性能的影响结果。砂浆样品由立陶宛公司生产的当地原材料制备。研究了砂浆样品在三个不同硬化期(7天、28天和90天)后的性能,如干体积密度、超声脉冲速度、毛细吸水率、抗压强度和抗折强度以及韧性。所应用的数学统计方法对改性砂浆样品的干体积密度与强度性能之间的相关性进行了详细预测。42.5R强度等级的波特兰水泥与5%至20%用量的SBR乳胶的组合似乎适合设计具有特定性能的耐久性结构。