Wu Dan, Xu Genghao, Tan Jing, Wang Xiao, Zhang Yilan, Ma Lei, Chen Wei, Wang Kai
College of New Materials and New Energies, Shenzhen Technology University, Shenzhen, 518118, China.
College of Engineering Physics, Shenzhen Technology University, Shenzhen, 518118, China.
Nanoscale. 2025 Apr 3;17(14):8239-8269. doi: 10.1039/d4nr03601h.
Short-wave infrared (SWIR) photodetectors (PDs) have a wide range of applications in the field of information and communication. Especially in recent years, with the increasing demand for consumer electronics, conventional semiconductor-based PDs alone are unable to cope with the ever-increasing market. Colloidal quantum dots (QDs) have attracted great interest due to their low fabrication cost, solution processability, and promising optoelectronic properties. In addition to advancements in synthesis methods and surface ligand engineering, the photoelectronic performance of QD-based SWIR PDs has been greatly improved due to developments in nanophotonic structural engineering, such as microcavities, localized and propagating surface plasmon resonant structures, and gratings for specific and high-performance detection application. The improvement in the performance of photoconductors, photodiodes, and phototransistors also enhances the performance of SWIR imaging sensors where they have been realized and demonstrated promising potential due to the direct integration of QD PDs with CMOS substrates. In addition, flexible manipulation of the QDs has been realized, thanks to their solution-processable capability. Therefore, a variety of large-scale production process methods have been examined including blade coating, flexible microcomb printing, ink-jet printing, spray deposition, . which can effectively reduce the cost and promote commercial application in consumer electronics. Finally, the current challenges and future development prospects of QD-based PDs are reviewed and could provide guidance for future design of the QDs PDs.
短波红外(SWIR)光电探测器(PDs)在信息与通信领域有着广泛的应用。特别是近年来,随着消费电子产品需求的不断增加,仅靠传统的基于半导体的光电探测器已无法应对日益增长的市场需求。胶体量子点(QDs)因其较低的制造成本、溶液可加工性和有前景的光电特性而备受关注。除了合成方法和表面配体工程方面的进展外,由于纳米光子结构工程的发展,如微腔、局域和传播表面等离子体共振结构以及用于特定和高性能检测应用的光栅,基于量子点的短波红外光电探测器的光电子性能得到了极大提高。光电导体、光电二极管和光电晶体管性能的提升也增强了短波红外成像传感器的性能,在这些传感器中,由于量子点光电探测器与CMOS衬底的直接集成,已经实现并展示出了有前景的潜力。此外,由于量子点的溶液可加工能力,已经实现了对其的灵活操控。因此,已经研究了多种大规模生产工艺方法,包括刮刀涂布、柔性微梳印刷、喷墨印刷、喷雾沉积等,这些方法可以有效降低成本并促进在消费电子产品中的商业应用。最后,对基于量子点的光电探测器当前面临的挑战和未来发展前景进行了综述,可为未来量子点光电探测器的设计提供指导。