Cyniak Jakub S, Kasprzak Artur
Faculty of Chemistry, Warsaw University of Technology, Noakowskiego Str. 3, 00-664 Warsaw, Poland.
ACS Omega. 2024 Dec 6;9(50):48870-48883. doi: 10.1021/acsomega.4c06566. eCollection 2024 Dec 17.
The design of environmentally friendly methods for synthesizing molecular receptors is an expanding area within applied organic chemistry. This work systematically summarizes advances in the mechanochemical synthesis of molecular chemoreceptors. It discusses key achievements related to the synthesis of chemoreceptors containing azine, Schiff base, thiosemicarbazone, hydrazone, rhodamine 6G, imide, or amide moieties. Additionally, it highlights the application potential of mechanochemically synthesized molecular chemoreceptors in the recognition of ions and small molecules, along with a discussion of the mechanisms of detection processes.
设计环境友好型分子受体合成方法是应用有机化学中一个不断发展的领域。这项工作系统地总结了分子化学感受器机械化学合成方面的进展。它讨论了与含有嗪、席夫碱、硫代氨基脲、腙、罗丹明6G、酰亚胺或酰胺部分的化学感受器合成相关的关键成就。此外,它还强调了机械化学合成的分子化学感受器在离子和小分子识别方面的应用潜力,以及对检测过程机制的讨论。