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基于淀粉样蛋白聚集的柔性、可拉伸多功能银纳米颗粒修饰棉织物用于电热和光热双驱动可穿戴加热器。

Flexible, stretchable multifunctional silver nanoparticles-decorated cotton textile based on amyloid-like protein aggregation for electrothermal and photothermal dual-driven wearable heater.

作者信息

Du Jiehao, Guo Zengpei, Yan Xue, Yao Yiting, Zhang Ruquan, Zhou Yingshan, Liu Xin, Shang Bin, Huang Jingjing, Gu Shaojin

机构信息

State Key Laboratory for New Textile Materials and Advanced Processing Technology, School of Materials Science and Engineering, Wuhan Textile University, Wuhan 430200, PR China.

State Key Laboratory for New Textile Materials and Advanced Processing Technology, School of Materials Science and Engineering, Wuhan Textile University, Wuhan 430200, PR China.

出版信息

Int J Biol Macromol. 2025 Mar;292:139124. doi: 10.1016/j.ijbiomac.2024.139124. Epub 2024 Dec 24.

DOI:10.1016/j.ijbiomac.2024.139124
PMID:39722396
Abstract

The design of multifunctional, high-performance wearable heaters utilizing textile substrates has garnered increasing attention, particularly in the development of body temperature and health monitoring devices. However, fabricating these multifunctional wearable heaters while simultaneously ensuring flexibility, air permeability, Joule heating performance, electromagnetic interference (EMI) shielding and antibacterial properties remains a significant challenge. This study utilizes phase transition lysozyme (PTL) film-mediated electroless deposition (ELD) technology to deposit silver nanoparticles (Ag NPs) on the cotton fabrics surface in a mild aqueous solution at room temperature, thereby constructing a wearable heater with long-term stability, high conductivity, and exceptional photothermal properties. The textiles enriched with Ag NPs exhibit remarkable electrothermal and photothermal dual-driven heating capabilities, achieving temperatures exceeding 110 °C within 50s under 2 V, or in merely a few seconds through photothermal conversion. Importantly, these textiles retain the intrinsic flexibility and breathability of the textile substrate. Furthermore, the amyloid-like protein Ag NP integrated textiles demonstrate excellent antibacterial properties, and exhibit a high EMI shielding efficiency of 50 dB within the frequency range of 8.2-12.4 GHz. Therefore, these multifunctional Ag NPs wearable heaters were expected to find applications in areas such as smart wearable clothing and future health management.

摘要

利用纺织基材设计多功能、高性能可穿戴加热器已引起越来越多的关注,尤其是在体温和健康监测设备的开发方面。然而,在制造这些多功能可穿戴加热器的同时,要确保其柔韧性、透气性、焦耳加热性能、电磁干扰(EMI)屏蔽和抗菌性能仍然是一项重大挑战。本研究利用相变溶菌酶(PTL)膜介导的化学沉积(ELD)技术,在室温下于温和的水溶液中,将银纳米颗粒(Ag NPs)沉积在棉织物表面,从而构建出具有长期稳定性、高导电性和优异光热性能的可穿戴加热器。富含Ag NPs的纺织品展现出卓越的电热和光热双驱动加热能力,在2 V电压下50秒内温度超过110°C,或通过光热转换仅需几秒钟。重要的是,这些纺织品保留了纺织基材固有的柔韧性和透气性。此外,类淀粉样蛋白Ag NP集成纺织品表现出优异的抗菌性能,并且在8.2 - 12.4 GHz频率范围内展现出50 dB的高EMI屏蔽效率。因此,这些多功能Ag NPs可穿戴加热器有望在智能可穿戴服装和未来健康管理等领域得到应用。

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